Conjugate phosphination of cyclic and acyclic acceptors using Rh(I)-phosphine or Rh(I)-carbene complexes. Probing the mechanism with chirality at the silicon atom or the phosphorus atom of the Si-P reagent

Tetrahedron

Volumn 65, Issue 33, 2009, Pages 6510-6518

  Trepohl, Verena T ^a   Fröhlich, Roland ^a   Oestreich, Martin ^a  

^a UNIVERSITY OF MÜNSTER   (Germany)

Author keywords

Conjugate addition; Homogeneous catalysis; Phosphorus; Reaction mechanism; Rhodium; Silicon

Indexed keywords

ACYCLIC ACCEPTOR; CARBENE; CYCLIC ACCEPTOR; PHOSPHINE; PHOSPHINIDE; PHOSPHORUS; REAGENT; RHODIUM; SILICON; TRANSITION ELEMENT; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHIRALITY; CONJUGATE; CONTROLLED STUDY; DIASTEREOISOMER; PHOSPHINATION; PRIORITY JOURNAL; RACEMIZATION; REACTION ANALYSIS; SILYLPHOSPHINE; STEREOCHEMISTRY; TRANSMETALATION;

EID: 67650245511     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tet.2009.04.038     Document Type: Article

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