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note
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12: C, 10.32%; H, 0.79%; N, 2.41%; Cu, 3.64%; P, 0.88%; W, 63.19%. Found: C, 10.47%; H, 0.66%; N, 2.39%; Cu, 3.54%; P, 0.82%; W, 63.04%. The infrared spectrum of 1 is explained in the supporting information (Fig. S2).
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+, and another one nitrogen atom (N4) was protonated for the requirement of charge balance. So the 4,4′-bpy ligand including N3 and N4, and the water molecule are disordered. The bond lengths and bond angels of the disordered water are restrained in the range of usual values. All the atoms were refined with anisotropic thermal parameters except the atoms of the disorder 4,4′-bpy, the disordered coordination water molecule, and all hydrogen atoms.
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