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1.998(9), Ir(1) - N(2) 2.014(7), Ir(1) - N(1) 2.017(7), Ir(1) - N(3) 2.060(7), Ir(1) - Cl(1) 2.363(2), Ir(1) - Cl(2) 2.480(2); C(25) - Ir(1) - N(2) 88.7(3), C(25) - Ir(1) - N(1)
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1.998(9), Ir(1) - N(2) 2.014(7), Ir(1) - N(1) 2.017(7), Ir(1) - N(3) 2.060(7), Ir(1) - Cl(1) 2.363(2), Ir(1) - Cl(2) 2.480(2); C(25) - Ir(1) - N(2) 88.7(3), C(25) - Ir(1) - N(1)
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Thick glass walled ampule sealed with a resealable high-vac PTFE valve
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Thick glass walled ampule sealed with a resealable high-vac PTFE valve.
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46
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84868984011
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13C NMR shifts were assigned on the basis of the free ligand and complexes 2a, b-Py
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13C NMR shifts were assigned on the basis of the free ligand and complexes 2a, b-Py
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