Dynamic behavior of intramolecularly base-stabilized phosphatetrylenes. insights into the inversion processes of trigonal pyramidal geramanium(II) and tin(II) centers

Organometallics

Volumn 28, Issue 12, 2009, Pages 3327-3337

  Izod, Keith ^a   Stewart, John ^a   Clark, Ewan R ^a   McFarlane, William ^a   Allen, Ben ^a   Clegg, William ^a   Harrington, Ross W ^a  

^a NEWCASTLE UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ADDUCT FORMATION; DFT CALCULATION; DIASTEREOMER; DIASTEREOMERS; DYNAMIC BEHAVIORS; DYNAMIC PROCESS; ENERGY DYNAMICS; EPIMERIZATION; GOOD YIELD; HETEROLEPTIC; HIGH TEMPERATURE; HOMOLEPTIC; INTERCONVERSION; INVERSION PROCESS; ION PAIRS; LITHIUM SALTS; LOW TEMPERATURES; MODEL COMPLEXES; MODEL COMPOUND; MULTI-ELEMENT; PHOSPHIDE LIGANDS; PHOSPHORUS ATOM; POLAR SOLVENTS; RAPID EQUILIBRIUM; SOLID-STATE STRUCTURES; VARIABLE-TEMPERATURE NMR;

ATOMS; CHELATION; GERMANIUM; LIGANDS; LITHIUM; NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOSPHORUS; PHOSPHORUS COMPOUNDS; PROBABILITY DENSITY FUNCTION; SILICON; SULFUR COMPOUNDS; TIN;

CRYSTAL ATOMIC STRUCTURE;

EID: 67449119463     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om8011757     Document Type: Article

References (69)

1. For reviews see: (a) Barrau, J.; Rima, G. Coord. Chem. Rev. 1998, 178-180, 593.
2. (b) Tokitoh, N.; Okazaki, R. Coord. Chem. Rev. 2000, 210, 251.
3. (c) Kira, M. J. Organomet. Chem. 2004, 689, 4475.
4. (d) Weidenbruch, M. Eur. J. Inorg. Chem. 1999, 373.
5. (e) Klinkhammer, K. W. In Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: New York, 2002; Vol. 2, pp 283-357.
6. (f) Veith, M. Angew. Chem., Int. Ed. Engl. 1987, 26, 1.
7. For reviews of N-heterocyclic silylenes see: (a) Hill, N. J.; West, R. J. Organomet. Chem. 2004, 689, 4165.
8. (b) Gehrhus, B.; Lappert, M. F. J. Organomet. Chem. 2001, 617, 209.
9. For a review of N-heterocyclic germylenes see: Kühl, O. Coord. Chem. Rev. 2004, 248, 411.
10. For leading references to diamidogermylenes, -stannylenes, and -plumbylenes see:(a) Fjeldberg, T.; Hope, H.; Lappert, M. F.; Power, P. P.; Thorne, A. J. J. Chem. Soc., Chem. Commun. 1983, 639.
11. (b) Olmstead, M. M.; Power, P. P. Inorg. Chem. 1984, 23, 413.
12. (c) Tang, Y.; Felix, A. M.; Zakharov, L. N.; Rheingold, A. L.; Kemp, R. A. Inorg. Chem. 2004, 43, 7239.
13. (d) Avent, A. G.; Drost, C.; Gehrus, B.; Hitchcock, P. B.; Lappert, M. F. Z. Anorg. Allg. Chem. 2004, 630, 2090.
14. (e) Gans-Eichler, T.; Gudat, D.; Nieger, M. Angew. Chem., Int. Ed. 2002, 41, 1888.
15. (f) Chorley, R. W.; Hitchcock, P. B.; Lappert, M. F.; Leung, W.-P.; Power, P. P.; Olmstead, M. M. Inorg. Chim. Acta 1992, 198, 203.
16. (g) Braunschweig, H.; Hitchcock, P. B.; Lappert, M. F.; Pierssens, L. J.-M. Angew. Chem., Int. Ed. Engl. 1994, 33, 1156.
17. (h) Lappert, M. F.; Slade, M. J.; Atwood, J. L.; Zaworotko, M. J. J. Chem. Soc., Chem. Commun. 1980, 621.
18. (i) Bazinet, P.; Yap, G. P. A.; Richeson, D. S. J. Am. Chem. Soc. 2001, 123, 11162.
19. Cowley, A. H.; Giolando, D. M.; Jones, R. A.; Nunn, C. M.; Power, J. M. Polyhedron 1988, 7, 1909.
20. Goel, S. C.; Chiang, M. Y.; Rauscher, D. J.; Buhro, W. E. J. Am. Chem. Soc. 1993, 115, 160.
21. Druckenbrodt, C.; du Mont, W.-W.; Ruthe, F.; Jones, P. G. Z. Anorg. Allg. Chem. 1998, 624, 590.
22. Driess, M.; Janoschek, R.; Pritzkow, H.; Rell, S.; Winkler, U. Angew. Chem., Int. Ed. 1995, 34, 1614.
23. Yao, S.; Brym, M.; Merz, K.; Driess, M. Organometallics 2008, 27, 3601.
24. Rivard, E.; Sutton, A. D.; Fettinger, J. C.; Power, P. P. Inorg. Chim. Acta 2007, 360, 1278.
25. Arif, A. M.; Cowley, A. H.; Jones, R. A.; Power, J. M. J. Chem. Soc., Chem. Commun. 1986, 1446.
26. For examples see: (a) Westerhausen, M.; Hausen, H.-D.; Schwarz, W. Z. Anorg. Allg. Chem. 1996, 622, 903.
27. (b) Westerhausen, M.; Krofta, M.; Wiberg, N.; Nöth, H.; Pfitzner, A. Z. Naturforsch. B 1998, 53, 1489.
28. (c) Westerhausen, M.; Hausen, H.-D.; Schwarz, W. Z. Anorg. Allg. Chem. 1995, 621, 877.
29. (d) Westerhausen, M.; Krofta, M.; Schneiderbauer, S.; Piotrowski, H. Z. Anorg. Allg. Chem. 2005, 631, 1391.
30. (e) Allan, R. E.; Beswick, M. A.; Cromhout, N. L.; Paver, M. A.; Raithby, P. R.; Trevithick, M.; Wright, D. S. Chem. Commun. 1996, 1501.
31. (f) Garcia, F.; Hahn, J. P.; McPartlin, M.; Pask, C. M.; Rothenberger, A.; Stead, M. L.; Wright, D. S. Organometallics 2006, 25, 3275.
32. Kapp, J.; Schade, C.; El-Nahasa, A. M.; Schleyer, P. von R.;
33. Angew. Chem., Int. Ed. Engl. 1996, 35, 2236.
34. Martin, D.; Baceiredo, A.; Gornitzka, H.; Schoeller, W. W.; Bertrand, G. Angew. Chem., Int. Ed. 2005, 44, 1700.
35. (a) Beachler, R. D.; Casey, J. P.; Cook, R. J.; Senkler, G. H., Jr.; Mislow, K. J. Am. Chem. Soc. 1987, 109, 338.
36. (b) Beachler, R. D.; Mislow, K. J. Am. Chem. Soc. 1971, 93, 773.
37. (c) Beachler, R. D.; Andose, J. D.; Stackhouse, J.; Mislow, K. J. Am. Chem. Soc. 1972, 94, 8060.
38. (d) Driess, M.; Merz, K.; Monse, C. Z. Anorg. Allg. Chem. 2000, 626, 2264.
39. Izod, K.; McFarlane, W.; Allen, B.; Clegg, W.; Harrington, R. W. Organometallics 2005, 24, 2157.
40. Denk, M. K.; Khan, M.; Lough, A. J.; Shuchi, K. Acta Crystallogr. Sect. C 1998, C54, 1830.
41. Ding, Y.; Roesky, H. W.; Noltemeyer, M.; Schmidt, H.-G.; Power, P. P. Organometallics 2001, 20, 1190.
42. Saur, I.; Miqueu, K.; Rima, G.; Barrau, J.; Lemierre, V.; Chrostowska, A.; Sotiropolous, J.-M.; Pfister-Guillouzo, G. Organometallics 2003, 22, 3143.
43. (a) Stender, M.; Phillips, A. D.; Power, P. P. Inorg. Chem. 2001, 40, 5314.
44. (b) Driess, M.; Yao, S.; Brym, M.; van Wullen, C. Angew. Chem., Int. Ed. 2006, 45, 4349.
45. (a) Becke, A. D. J. Chem. Phys. 1993, 98, 5648.
46. (b) Stephens, P. J.; Devlin, F. J.; Chablowski, C. F.; Frisch, M. J. J. Phys. Chem. 1994, 98, 11623.
47. (c) Hertwig, R. H.; Koch, W. Chem. Phys. Lett. 1997, 268, 345.
48. (a) Hay, P. J.; Wadt, W. R. J. Chem. Phys. 1985, 82, 270.
49. (b) Wadt, W. R.; Hay, P. J. J. Chem. Phys. 1985, 82, 284.
50. (c) Hay, P. J.; Wadt, W. R. J. Chem. Phys. 1985, 82, 299.
51. (a) Hariharan, P. C.; Pople, J. A. Theor. Chim. Acta 1973, 28, 213.
52. (b) Francl, M. M.; Petro, W. J.; Hehre, W. J.; Binkley, J. S.; Gordon, M. S.; DeFrees, D. J.; Pople, J. A. J. Chem. Phys. 1982, 77, 3654.
53. (a) Dixon, D. A.; Arduengo, A. J., III; Fukunaga, T. J. Am. Chem. Soc. 1986, 108, 2461.
54. (b) Dixon, D. A.; Arduengo, A. J., III J. Chem. Soc., Chem. Commun. 1987, 498.
55. (c) Dixon, D. A.; Arduengo, A. J., III J. Am. Chem. Soc. 1987, 109, 338.
56. (d) Schwerdtfeger, P.; Laakkonen, L. J.; Pyykkö, P. J. Chem. Phys. 1992, 96, 6807.
57. (e) Schwerdtfeger, P.; Hunt, P. Adv. Mol. Struct. Res. 1999, 5, 223.
58. (f) Schwerdtfeger, P.; Boyd, P. D. W.; Fischer, T.; Hunt, P.; Liddell, M. J. Am. Chem. Soc. 1994, 116, 9620.
59. (g) Göller, A.; Clark, T. Chem. Commun. 1997, 1033.
60. Clegg, W.; Doherty, S.; Izod, K.; Kagerer, H.; O'Shaughnessy, P.; Sheffield, J. M. J. Chem. Soc., Dalton Trans. 1999, 1825.
61. (a) SMART and SAINT software for CCD diffractometers; Bruker AXS Inc.: Madison, WI, 1997.
62. (b) CrysAlisPro; Oxford Diffraction Ltd.: Oxford, UK.
63. (c) Sheldrick, G. Acta Crystallogr., Sect. A 2008, 64, 112.
64. Frisch, M. J.; et al. Gaussian 03, Revision C.02; Gaussian, Inc.: Wallingford, CT, 2004.
65. (a) Head-Gordon, M.; Pople, J. A.; Frisch, M. J. Chem. Phys. Lett. 1988, 153, 503.
66. (b) Frisch, M. J.; Head-Gordon, M.; Pople, J. A. Chem. Phys. Lett. 1990, 166, 275.
67. (c) Frisch, M. J.; Head-Gordon, M.; Pople, J. A. Chem. Phys. Lett. 1990, 166, 281.
68. (d) Head-Gordon, M.; Head-Gordon, T. Chem. Phys. Lett. 1994, 220, 122.
69. (e) Saebo, S.; Almlof, J. Chem. Phys. Lett. 1989, 154, 83.