P(SiiPr3)3: The first trisilylphosphane derivative with an almost planar three-coordinated phosphorus atom

Zeitschrift fur Anorganische und Allgemeine Chemie

Volumn 626, Issue 11, 2000, Pages 2264-2268

  Driess, M ^a   Merz, K ^a   Monse C ^a  

^a RUHR UNIVERSITY BOCHUM   (Germany)

Author keywords

Inversion barrier; Phosphanes; Phosphorus; Rotational isomers; Silicon

Indexed keywords

EID: 0034357606     PISSN: 00442313     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3749(200011)626:11<2264::AID-ZAAC2264>3.0.CO;2-F     Document Type: Article

References (39)

1. a) Review: D. G. Gilheany, Chem. Rev. 1994, 94, 1339;
2. b) see also [7];
3. c) Holleman, Wiberg, Lehrbuch der An-organischen Chemie, de Gruyter, Berlin, 101. Auflage 1995, pp. 657.
4. W. Kutzelnigg, Angew. Chem. 1984, 96, 262; Angew. Chem. Int. Ed. Engl. 1984, 23, 272.
5. W. Kutzelnigg, Angew. Chem. 1984, 96, 262; Angew. Chem. Int. Ed. Engl. 1984, 23, 272.
6. a) J. M. Brown, Chem. Soc. Rev. 1993, 25;
7. b) Catalytic Asymmetrie Synthesis (Ed.: I. Ojima), VCH, New York, 1993;
8. c) Q. Jiang, Y. Jiang, D. Xiao, P. Cao, X. Zhang, Angew. Chem. 1998, 110, 1203; Angew. Chem. Int. Ed. Engl. 1998, 37, 1100.
9. c) Q. Jiang, Y. Jiang, D. Xiao, P. Cao, X. Zhang, Angew. Chem. 1998, 110, 1203; Angew. Chem. Int. Ed. Engl. 1998, 37, 1100.
10. F. G. N. Cloke, P. B. Hitchcock, P. Hunnable, J. F. Nixon, L. Nyulászi, E. Niecke, V. Thelen, Angew. Chem. 1998, 770, 1139; Angew. Chem. Int. Ed. Engl. 1998, 37.
11. F. G. N. Cloke, P. B. Hitchcock, P. Hunnable, J. F. Nixon, L. Nyulászi, E. Niecke, V. Thelen, Angew. Chem. 1998, 770, 1139; Angew. Chem. Int. Ed. Engl. 1998, 37.
12. Reviews: a) R. T. Paine, H. Nöth, Chem. Rev. 1995, 95, 343 ;
13. b) H. V. Dias Rasika, P. P. Power, Angew. Chem. 1987, 99, 1320 ; Angew. Chem. Int. Ed. Engl. 1987, 26, 1270.
14. b) H. V. Dias Rasika, P. P. Power, Angew. Chem. 1987, 99, 1320 ; Angew. Chem. Int. Ed. Engl. 1987, 26, 1270.
15. G. Fritz, E. Matern, H. Krautscheid, R. Ahlrichs, J. W. Olkowska, J. Pikies, Z. Anorg. Allg. Chem. 1999, 625, 1604.
16. S. Nagase, General and Theoretical Aspects in The Chemistry of Organic arsenic, antimony and bismuth compounds (Ed.: S. Patai), Wiley 1994, pp. 1 and references cited therein.
17. a) B. Beagley, A. R. Conrad, Trans. Faraday Soc. 1970, 66, 2740;
18. b) M. J. Barrow, E. A. V. Ebsworth, J. Chem. Soc., Dalton Trans. 1984, 563;
19. c) see also [9 d], pp. 254.
20. a) M. A. Petrie, P. P. Power, J. Chem. Soc., Dalton Trans. 1993, 1737;
21. b) G. A. Forsyth, D. W. H. Rankin, H. E. Robertson, J. Mol. Struct. 1990, 239, 209;
22. c) J. Bruckmann, C. Krüger, Acta Crystallogr. 1995, C51, 1152;
23. d) Review: W. S. Sheldrick, Structural chemistry of organic silicon compounds in The chemistry of organic silicon compounds (Eds.: S. Patai, Z. Rappoport), Wiley, New York 1989, part 1, pp. 260.
24. M. Westerhausen, R. Low, W. Schwarz, J. Organomet. Chem. 1996, 513, 213.
25. a) M. Driess, H. Pritzkow, S. Martin, S. Rell, D. Fenske, G. Baum, Angew. Chem. 1996, 108, 1064; Angew. Chem. Int. Ed. Engl. 1996, 35, 986;
26. a) M. Driess, H. Pritzkow, S. Martin, S. Rell, D. Fenske, G. Baum, Angew. Chem. 1996, 108, 1064; Angew. Chem. Int. Ed. Engl. 1996, 35, 986;
27. b) M. Driess, U. Hoffmanns, S. Martin, K. Merz, H. Pritzkow, Angew. Chem. 1999, 111, 2906; Angew. Chem. Int. Ed. Engl. 1999, 38, 2733;
28. b) M. Driess, U. Hoffmanns, S. Martin, K. Merz, H. Pritzkow, Angew. Chem. 1999, 111, 2906; Angew. Chem. Int. Ed. Engl. 1999, 38, 2733;
29. c) Review: M. Driess, Acc. Chem. Res. 1999, 32, 1017.
30. G. Fritz, W. Hölderich, H. Schäfer, Z. Anorg. Allg. Chem. 1974, 407, 266.
31. 31P NMR Spectroscopy in Stereochemical Analysis (Eds.: L. A. Quin, J. G. Verkade), VCH, Weinheim 1987, pp. 446.
32. a) J. A. Pople, D. P. Santry, Mol. Phys. 1964, 8, 1;
33. b) see also [13], pp. 425.
34. K. D. Crosbie, G. M. Sheldrick, Mol. Phys. 1971, 20, 317.
35. Semiempirical calculations (MNDO) were performed using the TITAN program: M. D. Beachy, Y. Cao, R. B. Murphy, J. K. Perry, W. T. Pollard, M. N. Ringnalda, G. R. Vacek, J. R. Wright, Schrödinger Inc. 1999; B. J. Deppmeier, A. J. Driessen, T. S. Heere, W. J. Heere, J. A. Johnson, P. E. Klunzinger, L. Lou, J. Yu, Wavefunction Inc. 1999.
36. Semiempirical calculations (MNDO) were performed using the TITAN program: M. D. Beachy, Y. Cao, R. B. Murphy, J. K. Perry, W. T. Pollard, M. N. Ringnalda, G. R. Vacek, J. R. Wright, Schrödinger Inc. 1999; B. J. Deppmeier, A. J. Driessen, T. S. Heere, W. J. Heere, J. A. Johnson, P. E. Klunzinger, L. Lou, J. Yu, Wavefunction Inc. 1999.
37. J. Siegel, A. Gutiérrez, W. B. Schweizer, O. Ermer, K. Mislow, J. Am. Chem. Soc. 1986,108, 1569.
38. a) U. Winkler, PhD-Thesis, Heidelberg 1994;
39. b) M. Driess, U. Winkler, H. Pritzkow, unpublished results.