A fast and easy approach to the synthesis of Zeise's salt using microwave heating

Inorganic Chemistry Communications

Volumn 12, Issue 5, 2009, Pages 341-342

  Shoemaker, Krista A ^a   Leadbeater, Nicholas E ^a  

^a UNIVERSITY OF CONNECTICUT   (United States)

Author keywords

Alkene complex; Microwave; Platinum; Zeise's salt

Indexed keywords

EID: 67349258607     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2009.02.015     Document Type: Article

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33. Reactions were performed using a CEM Discover microwave unit. This consists of a continuous focused microwave power delivery system with operator selectable power output from 0 to 300 W. Reactions were performed either in 10 mL or 80 mL capacity sealed tubes. The temperature of the contents of the vessel was monitored using an IR sensor located underneath the reaction vessel or a fiber-optic temperature probe inserted directly into the reaction mixture. Pressure was controlled by a load cell connected directly to the vessel. The contents of the reaction vessel are stirred by means of an electromagnet located below the floor of the microwave cavity and a Teflon-coated magnetic stir bar in the vessel. Temperature, pressure and power profiles were monitored using commercially available software provided by the microwave manufacturer. For loading reaction vessels with gas, either a commercially available gas-loading interface or an in-house built interface was used.
34. 1 J Pt = 195 Hz).