Kinetics and computational studies of an aminosilane reaction with a silsesquioxane silanol

Journal of Physical Chemistry A

Volumn 113, Issue 24, 2009, Pages 6612-6619

  Frei, Reto ^a   Blitz, Jonathan P ^a   Gun'ko, Vladimir M ^b   Frost, Bradley E ^a   Sergeev, Victor S ^b  

^a EASTERN ILLINOIS UNIVERSITY   (United States)

^b INSTITUTE OF SURFACE CHEMISTRY   (Ukraine)

Author keywords

[No Author keywords available]

Indexed keywords

AMINOSILANE; CATALYTIC REACTIONS; COMPETITIVE EFFECTS; COMPUTATIONAL RESULTS; COMPUTATIONAL STUDIES; DYNAMIC CALCULATIONS; EXPERIMENTAL DATA; FTIR; HIGHER TEMPERATURES; HYDROGEN BONDINGS; POLAR SOLVENTS; PREREACTION COMPLEXES; RATE LIMITING; SECOND ORDERS; SILANOL; SILSESQUIOXANE; TETRAHYDROFURAN; TRANSFER STAGES;

CATALYSIS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; HEXANE; HYDROGEN; HYDROGEN BONDS; REACTION RATES; SILICA;

ACTIVATION ENERGY;

(3 AMINOPROPYL)DIMETHYLMETHOXYSILANE; (3-AMINOPROPYL)DIMETHYLMETHOXYSILANE; 3,5,7,9,11,13,15 HEPTACYCLOPENTYLPENTACYCLO(9.5.1.1(3,9).1(5,15).1(7,13))OCTASILOXAN 1 OL; 3,5,7,9,11,13,15-HEPTACYCLOPENTYLPENTACYCLO(9.5.1.1(3,9).1(5,15).1(7,13))OCTASILOXAN-1-OL; SILANE DERIVATIVE; SILICON DIOXIDE; SILOXANE;

ARTICLE; CHEMICAL MODEL; CHEMISTRY; COMPUTER SIMULATION; INFRARED SPECTROSCOPY; KINETICS; QUANTUM THEORY; TEMPERATURE;

COMPUTER SIMULATION; KINETICS; MODELS, CHEMICAL; QUANTUM THEORY; SILANES; SILICON DIOXIDE; SILOXANES; SPECTROSCOPY, FOURIER TRANSFORM INFRARED; TEMPERATURE;

EID: 67049096246     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp9002998     Document Type: Article

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