1,3-Dipolar cycloaddition of diazoalkanes to (S)-(+)-3-[(4-methylphenyl) sulfinyl]-5,6-dihydropyran-2-one. Synthesis of optically pure cyclopropanes by denitrogenation of sulfinyl and sulfonyl pyrazolines

Journal of Organic Chemistry

Volumn 74, Issue 10, 2009, Pages 3820-3826

  Cruz, David Cruz ^a   Yuste, Francisco ^a   Martín, M Rosario ^b   Tito, Amelia ^b   García Ruano, José L ^b  

^a UNIVERSIDAD NACIONAL AUTÓNOMA DE MÉXICO   (Mexico)

^b UNIVERSIDAD AUTÓNOMA DE MADRID   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMISTRY; ORGANIC COMPOUNDS;

1 ,3-DIPOLARCYCLOADDITION; 4-METHYLPHENYL; CHEMICAL EQUATIONS; CHEMO-SELECTIVITY; DENITROGENATION; DIAZOALKANES; DIAZOMETHANES; FACIAL SELECTIVITY;

PROPANE;

2 PYRONE DERIVATIVE; 3 [(4 METHYLPHENYL)SULFINYL] 5,6 DIHYDROPYRAN 2 ONE; CYCLOPROPANE DERIVATIVE; DIAZOMETHANE; NITROGEN; PYRAZOLINE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CYCLOADDITION; DECOMPOSITION; DENITROGENATION; ENANTIOSELECTIVITY; STEREOCHEMISTRY; SYNTHESIS;

EID: 65949099316     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo900525s     Document Type: Article

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