Carbene fragmentation in the bicyclo[3.1.0]hexyl system: Disconnecting the trishomocyclopropenyl cation

Organic Letters

Volumn 6, Issue 6, 2004, Pages 981-983

  Moss, Robert A ^a   Fu, Xiaolin ^a  

^a RUTGERS UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

2 BICYCLO[3.1.0]HEXENE; 2 BICYCLO[3.1.0]HEXYL CHLORIDE DERIVATIVE; 3 BICYCLO[3.1.0]HEXYL CHLORIDE DERIVATIVE; 3 BICYCLO[3.1.0]HEXYLOXYCHLOROCARBENE; BICYCLO COMPOUND; CARBENE; CATION; CHLORINE DERIVATIVE; PROPYLENE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; FRAGMENTATION REACTION; KINETICS; SYNTHESIS;

EID: 1642487630     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol040001m     Document Type: Article

References (21)

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12. 4) for 12.
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16. 12.
17. Similar distinctions are maintained in the fragmentations of menthyl-and neomenthyloxychlorocarbenes: Moss, R. A.; Johnson, L. A.; Kacprzynski, M.; Sauers, R. R. J. Org. Chem. 2003, 68, 5114.
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20. 19 and proceed via tight ion pairs resembling 16.
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