Enzymatic Synthesis of Ethyl Palmitate in Supercritical Carbon Dioxide

Industrial and Engineering Chemistry Research

Volumn 43, Issue 7, 2004, Pages 1568-1573

  Kumar, Rajnish ^a   Madras, Giridhar ^a   Modak, Jayant ^a  

^a INDIAN INSTITUTE OF SCIENCE   (India)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON DIOXIDE; ETHANOL; REACTION KINETICS; SYNTHESIS (CHEMICAL);

ENZYME LOADING; REACTION RATES;

ENZYMES;

ALCOHOL; CARBON DIOXIDE; PALMITIC ACID; PALMITIC ACID ETHYL ESTER; SOLVENT; TRIACYLGLYCEROL LIPASE; WATER;

ENZYME; ESTERIFICATION; PROCESSING TECHNIQUE; SUPERCRITICAL CARBON DIOXIDE; SYNTHESIS;

ARTICLE; CONCENTRATION RESPONSE; DOWNSTREAM PROCESSING; ENZYME MECHANISM; ENZYME SUBSTRATE; ESTERIFICATION; QUANTUM YIELD; SUPERCRITICAL FLUID; SYNTHESIS; TEMPERATURE DEPENDENCE;

EID: 1842614157     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie034032h     Document Type: Article

References (24)

1. Begley, S.; Springen, K.; Hager, M. Beyond Vitamins. Newsweek 1994, 123 (17), 45.
2. Mann, C.; Staba, J. The Chemistry, Pharmacology, and Commercial Formulations of Chamomile. In Herbs, Spices, and Medicinal Plants. Recent Advances in Botany, Horticulture, and Pharmacology; Craker, L. E., and Simon, J. E., Eds.; Oryx Press: Phoenix, AZ, 1986, p 233.
3. Krishna, S. H.; Manohar, B.; Divakar, S.; Prapulla, S. G.; Karnath, N. G. Optimization of Isoamyl Acetate Production by Using Immobilized Lipase from Mucor mehei by Response Surface Methodology. Enzyme Microb. Technol. 2000, 26, 131.
4. Langrand, G.; Triantaphylides, C.; Barrati, J. Lipase Catalyzed Formation of Flavor Esters. Biotechnol. Lett. 1988, 10, 549.
5. Langrand, G.; Rondot, N.; Triantaphylides, C.; Barrati, J. Short Chain Flavor Ester Synthesis by Microbial Lipases. Biotechnol. Lett. 1990, 12, 581.
6. Norin, M.; Boutelje, J.; Holmberg, E.; Hult, K. Lipase Immobilized by Adsorption: Effect of Support Hydrophobicity on the Reaction Rate of Esters Synthesis in Cyclohexane. Appl. Microbiol. Biotechnol. 1998, 28, 527.
7. Ison, A. P.; Macrae, A. R.; Smith, C. G.; Bosley, J. Mass transfer effect in solvent free fat interesterification reactions: Influences on catalyst design. Biotechnol. Bioeng. 1994, 43, 122.
8. Goma-Doncescu, N.; Legoy, M. D. An original transesterification route for fatty acid ester production from vegetable oils in a solvent-free system. J. Am. Oil Chem. Soc. 1997, 74, 1137-1143.
9. Trani, M.; Ergan, F.; Andre, G. Lipase-catalyzed production of wax esters. J. Am. Oil Chem. Soc. 1991, 68, 20.
10. De, B. K.; Bhattacharyya, D. K.; Bandhu, C. Enzymatic synthesis of fatty alcohol esters by alcoholysis. J. Am. Oil Chem. Soc. 1999, 76, 451.
11. Srivastava, S.; Modak, J. M.; Madras, G. Enzymatic synthesis of flavors in supercritical carbon dioxide. Ind. Eng. Chem. Res. 2002, 41, 1940.
12. Capewell, A.; Wendel, V.; Bornscheuer, U.; Meyer, H. H.; Scheper, T. Lipase-catalyzed kinetic resolution of 3-hydroxy esters in organic solvents and supercritical carbon dioxide. Enzyme Microb. Technol. 1996, 19, 181.
13. Erickson, J. C.; Schyns, P.; Cooney, C. L. Effect of pressure on an enzymatic-reaction in a supercritical fluid. AIChE. J. 1990, 36, 299.
14. Chulalaksananukul, W.; Jean-Stephane, C.; Combes, D. Grenyl acetate synthesis by lipase-catalysed transesterification in supercritical carbon dioxide. Enzyme Microb. Technol. 1993, 15, 691.
15. Chaudhary, A. K.; Beckman, E. J.; Russell, A. J. Rational control of polymer molecular weight and dispersity during enzyme-catalyzed polyester synthesis in supercritical fluids. J. Am. Chem. Soc. 1995, 117, 3728.
16. Chulalaksananukul, W.; Jean-Stephane, C.; Combes, D. Kinetics of grenyl acetate synthesis by lipase-catalysed transesterification in n-hexane. Enzyme Microb. Technol. 1992, 14, 293.
17. 2. Biotechno. Bioeng. 1992, 39, 273.
18. Gracia, T.; Sanchen, N.; Martinez, M.; Aracil, J. Enzymatic synthesis of fatty esters. Part I. Kinetic approach. Enzyme Microb. Technol. 1999, 25, 584.
19. Kamat, S.; Barrera, J.; Beckman, E. J.; Russell, A. J. Biocatalytic synthesis of acrylates in organic solvents and supercritical fluids. I. Optimization of enzyme environment. Biotechnol. Bioeng. 1992, 40, 158.
20. Dumont, T.; Barth, D.; Corbier, C.; Branlant, G.; Perrut, M. Enzymatic reaction kinetics: Comparison in an organic solvent and supercritical carbon dioxide. Biotechnol. Bioeng. 1992, 39, 329.
21. Mesiano, A. J.; Beckman, E. J.; Russell, A. J. Supercritical biocatalysis. Chem. Rev. 1999, 99, 623.
22. Zaks, A.; Klibanov, A. M. Enzymatic catalysis in nonaqueous solvents J. Biol. Chem. 1988, 263, 3194.
23. Miller, D. A.; Blanch, H. W.; Prausnitz, J. M. Enzyme-catalyzed interesterification of triglycerides in supercritical carbon dioxide. Ind. Eng. Chem. Res. 1991, 30, 939.
24. Dumont, T.; Barth, D.; Perrut, M. Proceedings of the 2nd International Symposium on Supercritical Fluids; Johns Hopkins University, Baltimore, MD, 1991; McHugh, M. A., Ed.; p 150.