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51449114903
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32044449383
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15
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0038235605
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1,2-Phenylene-bridged porphyrin dimers have been mainly synthesized by stepwise acid-catalyzed cyclization reactions;
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1,2-Phenylene-bridged porphyrin dimers have been mainly synthesized by stepwise acid-catalyzed cyclization reactions;. Meier H., Kobuke Y., and Kugimiya S. J. Chem. Soc. Chem. Commun. (1989) 923-924
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Meier, H.1
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16
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33748215719
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Osuka A., Nakajima S., Nagata T., Maruyama K., and Toriumi K. Angew. Chem., Int. Ed. Engl. 30 (1991) 582-584
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Osuka, A.1
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Maruyama, K.4
Toriumi, K.5
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17
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0542372293
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Therien et al. have prepared it by the cobalt-mediated alkyne trimerization reaction
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Naruta Y., Sasayama M.-a., and Sasaki T. Angew. Chem., Int. Ed. Engl. 33 (1994) 1839-1841 Therien et al. have prepared it by the cobalt-mediated alkyne trimerization reaction
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Naruta, Y.1
Sasayama, M.-a.2
Sasaki, T.3
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20
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65549090458
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note
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17) ppm.
-
-
-
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23
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58849101382
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Bringmann G., Götz D.C.G., Gulder T.A.M., Gehrke T.H., Bruhn T., Kupfer T., Radacki K., Braunschweig H., Heckmann A., and Lambert C. J. Am. Chem. Soc. 130 (2008) 17812-17825
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Bringmann, G.1
Götz, D.C.G.2
Gulder, T.A.M.3
Gehrke, T.H.4
Bruhn, T.5
Kupfer, T.6
Radacki, K.7
Braunschweig, H.8
Heckmann, A.9
Lambert, C.10
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24
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2042507954
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This is presumably due to an activation of the boron agent by intermediate formation of a quaternary boronate anion.
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This is presumably due to an activation of the boron agent by intermediate formation of a quaternary boronate anion. Miyaura N., and Suzuki A. Chem. Rev. 95 (1995) 2457-2483
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Miyaura, N.1
Suzuki, A.2
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25
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65549164694
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Compound 2b: 1H NMR (600 MHz, THF-d8) δ 9.67 (br, 2H, meso, 9.56 (d, J, 5.0 Hz, 4H, β, 8.92 (d, J, 5.0 Hz, 4H, β, 8.63 (m, 2H, Ph, 8.60 (d, J, 5.0 Hz, 4H, β, 8.57 (d, J, 5.0 Hz, 4H, β, 8.16 (m, 2H, Ph, 7.81 (dd, J, 7.3 Hz, 1.5 Hz, 4H, Ar, 7.65 (dd, J, 7.3 Hz, 1.5 Hz, 4H, Ar, 7.53 (dd, J, 7.3 Hz, 1.5 Hz, 4H, Ar, 7.48 (dd, J, 7.3 Hz, 1.5 Hz, 4H, Ar, 2.97 (t, J, 8.2 Hz, 8H, C8H17, 1.97 (tt, J, 8.2 Hz, 8.2 Hz, 8H, C8H17, 1.64-1.41 (m, 40H, C8H17, and 0.97 (t, J, 8.3 Hz, 12H, C8H17) ppm; ESI-TOF MS m/z 1574.7089, calcd for C102H106N8Zn2, 1574.7109; UV-Vis (CH2Cl2, λmax, 404, and 552 nm, THF, 409, and 555 nm; Fluorescence (CH2Cl2, λex, 404 nm) λem, 608 and 653 nm, THF, λex
-
em = 605 and 657 nm.
-
-
-
-
26
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65549151704
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note
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w (all data) = 0.1722, GOF = 1.038. CCDC 714770.
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-
-
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28
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65549166339
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note
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em = 656 and 718 nm.
-
-
-
-
29
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65549156510
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note
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em = 640 nm.
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