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Volumn 50, Issue 26, 2009, Pages 3333-3337

Facile synthesis and photophysical properties of 1,2-phenylene-bridged porphyrin dimers

Author keywords

Cross coupling; Exciton coupling; Oligomers; Porphyrinoid

Indexed keywords

BENZENE DERIVATIVE; DIMER; OLIGOMER; PALLADIUM; PORPHYRIN DERIVATIVE;

EID: 65549137658     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2009.02.081     Document Type: Article
Times cited : (13)

References (29)
  • 15
    • 0038235605 scopus 로고
    • 1,2-Phenylene-bridged porphyrin dimers have been mainly synthesized by stepwise acid-catalyzed cyclization reactions;
    • 1,2-Phenylene-bridged porphyrin dimers have been mainly synthesized by stepwise acid-catalyzed cyclization reactions;. Meier H., Kobuke Y., and Kugimiya S. J. Chem. Soc. Chem. Commun. (1989) 923-924
    • (1989) J. Chem. Soc. Chem. Commun. , pp. 923-924
    • Meier, H.1    Kobuke, Y.2    Kugimiya, S.3
  • 17
    • 0542372293 scopus 로고
    • Therien et al. have prepared it by the cobalt-mediated alkyne trimerization reaction
    • Naruta Y., Sasayama M.-a., and Sasaki T. Angew. Chem., Int. Ed. Engl. 33 (1994) 1839-1841 Therien et al. have prepared it by the cobalt-mediated alkyne trimerization reaction
    • (1994) Angew. Chem., Int. Ed. Engl. , vol.33 , pp. 1839-1841
    • Naruta, Y.1    Sasayama, M.-a.2    Sasaki, T.3
  • 20
    • 65549090458 scopus 로고    scopus 로고
    • note
    • 17) ppm.
  • 24
    • 2042507954 scopus 로고
    • This is presumably due to an activation of the boron agent by intermediate formation of a quaternary boronate anion.
    • This is presumably due to an activation of the boron agent by intermediate formation of a quaternary boronate anion. Miyaura N., and Suzuki A. Chem. Rev. 95 (1995) 2457-2483
    • (1995) Chem. Rev. , vol.95 , pp. 2457-2483
    • Miyaura, N.1    Suzuki, A.2
  • 25
    • 65549164694 scopus 로고    scopus 로고
    • Compound 2b: 1H NMR (600 MHz, THF-d8) δ 9.67 (br, 2H, meso, 9.56 (d, J, 5.0 Hz, 4H, β, 8.92 (d, J, 5.0 Hz, 4H, β, 8.63 (m, 2H, Ph, 8.60 (d, J, 5.0 Hz, 4H, β, 8.57 (d, J, 5.0 Hz, 4H, β, 8.16 (m, 2H, Ph, 7.81 (dd, J, 7.3 Hz, 1.5 Hz, 4H, Ar, 7.65 (dd, J, 7.3 Hz, 1.5 Hz, 4H, Ar, 7.53 (dd, J, 7.3 Hz, 1.5 Hz, 4H, Ar, 7.48 (dd, J, 7.3 Hz, 1.5 Hz, 4H, Ar, 2.97 (t, J, 8.2 Hz, 8H, C8H17, 1.97 (tt, J, 8.2 Hz, 8.2 Hz, 8H, C8H17, 1.64-1.41 (m, 40H, C8H17, and 0.97 (t, J, 8.3 Hz, 12H, C8H17) ppm; ESI-TOF MS m/z 1574.7089, calcd for C102H106N8Zn2, 1574.7109; UV-Vis (CH2Cl2, λmax, 404, and 552 nm, THF, 409, and 555 nm; Fluorescence (CH2Cl2, λex, 404 nm) λem, 608 and 653 nm, THF, λex
    • em = 605 and 657 nm.
  • 26
    • 65549151704 scopus 로고    scopus 로고
    • note
    • w (all data) = 0.1722, GOF = 1.038. CCDC 714770.
  • 28
    • 65549166339 scopus 로고    scopus 로고
    • note
    • em = 656 and 718 nm.
  • 29
    • 65549156510 scopus 로고    scopus 로고
    • note
    • em = 640 nm.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.