New alkenyl-substituted group 4 C-ansa-metallocene complexes. Reactivity of the substituent at the carbon ansa bridge

Journal of Organometallic Chemistry

Volumn 694, Issue 13, 2009, Pages 1959-1970

  Antiñolo, Antonio ^a   Fernández Galán, Rafael ^a   Molina, Noelia ^a   Otero, Antonio ^a   Rivilla, Iván ^a   Rodríguez, Ana M ^a  

^a UNIVERSITY OF CASTILLA LA MANCHA   (Spain)

Author keywords

Hydroboration; Hydrogenation; Hydrosilylation; Metallocenes; Titanium; Zirconium

Indexed keywords

ALKENYL; ANSA-METALLOCENE; ANSA-METALLOCENE COMPLEXES; CATALYTIC CONDITIONS; DIALKYL COMPLEXES; DOUBLE BONDS; GRIGNARD REAGENTS; HYDROBORATION; HYDROBORATION REACTIONS; HYDROGENATION PRODUCTS; HYDROSILYLATION REACTIONS; INSERTION REACTIONS; MAGNESOCENE; METALLOCENES; MOLAR EQUIVALENTS; PHENYL ISOCYANATES; SI-O-SI BONDS; SINGLE-CRYSTAL X-RAY DIFFRACTIONS; SUBSTITUTED GROUPS; WILKINSON'S CATALYSTS; ZIRCONOCENE COMPLEXES;

BAYESIAN NETWORKS; HYDROGENATION; HYDROSILYLATION; ISOMERS; METAL COMPLEXES; ORGANOMETALLICS; SILANES; TITANIUM; ZIRCONIUM;

ZIRCONIUM COMPOUNDS;

EID: 65449155088     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2009.01.038     Document Type: Article

References (63)

1. Brintzinger H.-H., Fischer D., Mülhaupt R., Rieger B., and Waymouth R.M. Angew. Chem., Int. Ed. Engl. 34 (1995) 1143-1170
2. Kaminsky W. J. Chem. Soc., Dalton Trans. (1998) 1413-1418
3. Soga K., and Shiono T. Prog. Polym. Sci. 22 (1997) 1503-1542
4. Alt H.G., and Köppl A. Chem. Rev. 100 (2000) 1205-1222
5. Coates G.W. Chem. Rev. 100 (2000) 1223-1252
6. Resconi L., Cavallo L., Fait A., and Piemontesi F. Chem. Rev. 100 (2000) 1253-1346
7. Brintzinger H.H., Fischer D., Mülhaupt R., Rieger B., and Waymouth R.M. Angew. Chem., Int. Ed. Engl. 34 (1995) 1143-1170
8. Prashar S., Antiñolo A., and Otero A. Coord. Chem. Rev. 250 (2006) 133-154
9. In: Abel E.W., Stone F.G.A., and Wilkinson G. (Eds). Comprehensive Organometallic Chemistry II vol. 4 (1995), Pergamon Press, Oxford, UK
10. Rieger B., Jany G., Fawzi R., and Steimann M. Organometallics 13 (1994) 647-653
11. Tian J., Soo-Ko Y., Metcalf R., Feng Y., and Collins S. Macromolecules 34 (2001) 3120-3122
12. Van Looveren L.K., Geysen D.F., Vercruysse K.A., Wouters B.H., Grobet P.J., and Jacobs P.A. Angew. Chem., Int. Ed. 37 (1998) 517-520
13. Tudor J., and O'Hare D. Chem. Commun. (1997) 603-604
14. Hlatky G.G. Chem. Rev. 100 (2000) 1347-1376
15. Fink G., Steinmetz B., Zechlin J., Przybyla C., and Tesche B. Chem. Rev. 100 (2000) 1377-1390
16. Lee B.Y., and Oh J.S. Macromolecules 33 (2000) 3194-3195
17. Galan-Fereres M., Koch T., Hey-Hawkins E., and Eisen M.S. J. Organomet. Chem. 580 (1999) 145-155
18. Lee B.Y., and Oh J.S. J. Organomet. Chem. 552 (1998) 313-317
19. Yamaguchi Y., Suzuki N., Mise T., and Wakatsuki Y. Organometallics 18 (1999) 996-1001
20. Zhu H., Jin G.-X., and Hu N. J. Organomet. Chem. 655 (2002) 167-171
21. Takayama C., Yamaguchi Y., Mise T., and Suzuki N. J. Chem. Soc., Dalton Trans. (2001) 948-953
22. Huhn T., Suzuki N., Yamaguchi Y., Mise T., Chihara T., and Wakatsuki Y. Chem. Lett. (1997) 1201-1202
23. D. Seyferth, R. Wyrwa, US Patent 5969073, 1999.
24. Miller C.J., and O'Hare D. Chem. Commun. (2004) 1710-1711
25. Zhang J., Wang X., and Jin G.-X. Coord. Chem. Rev. 250 (2006) 95-109
26. Suzuki N., Yu J., Shioda N., Asami H., Nakamura T., Huhn T., Fukuoka A., Ichikawa M., Saburi M., and Wakatsuki Y. Appl. Catal. A 224 (2002) 63-75
27. D. Seyferth, R. Wyrwa, US Patent 5969073, 1999.
28. Alt H.G., Ernst R., and Böhmer I. J. Mol. Catal. A: Chem. 191 (2003) 177-185
29. Soga K., Arai T., Nozawa H., and Uozumi T. Macromol. Symp. 97 (1995) 53
30. Alt H.G., Schertl P., and Köppl A. J. Organomet. Chem. 568 (1998) 263-269
31. Iiskola E.I., Timonen S., Pakkanen T.T., Härkki O., Lehmus P., and Seppälä J.V. Macromolecules 30 (1997) 2853-2859
32. Antiñolo A., López-Solera I., Orive I., Otero A., Prashar S., Rodríguez A.M., and Villaseñor E. Organometallics 20 (2001) 71-78
33. Antiñolo A., López-Solera I., Otero A., Prashar S., Rodríguez A.M., and Villaseñor E. Organometallics 21 (2002) 2460-2467
34. Antiñolo A., Fernández-Galán R., Gallego B., Otero A., Prashar S., and Rodríguez A.M. Eur. J. Inorg. Chem. (2003) 2626-2632
35. Antiñolo A., Fajardo M., Gómez-Ruiz S., López-Solera I., Otero A., and Prashar S. Organometallics 23 (2004) 4062-4069
36. Gómez-Ruiz S., Prashar S., Fajardo M., Antiñolo A., Otero A., Maestro M.A., Volkis V., Eisen M.S., and Pastor C.J. Polyhedron 24 (2005) 1298-1313
37. Polo-Cerón D., Gómez-Ruiz S., Prashar S., Fajardo M., Antiñolo A., Otero A., López-Solera I., and Reyes M.L. J. Mol. Catal. A 268 (2007) 264-276
38. Antiñolo A., Fernández-Galán R., Otero A., Prashar S., Rivilla I., Rodríguez A.M., and Maestro M.A. Organometallics 23 (2004) 5108-5111
39. Antiñolo A., Fernández-Galán R., Otero A., Prashar S., Rivilla I., and Rodríguez A.M. J. Organomet. Chem. 691 (2006) 2924-2932
40. Antiñolo A., Fajardo M., Gómez-Ruiz S., López-Solera I., Otero A., Prashar S., and Rodríguez A.M. J. Organomet. Chem. 683 (2003) 11-22
41. Polo-Cerón D., Gómez-Ruiz S., Prashar S., Fajardo M., Antiñolo A., and Otero A. Eur. J. Inorg .Chem. (2007) 4445-4455
42. Erker G., Nolte R., Aul R., Wilker S., Krüger C., and Noe R. J. Am. Chem. Soc. 113 (1991) 7594-7602
43. Erker G., and Aul R. Chem. Ber. 124 (1991) 1301-1310
44. Spence R.E.V.H., and Piers W.E. Organometallics 14 (1995) 4617-4624
45. Piers W.E., Sun Y., and Lee L.W.M.T. Top. Catal. 7 (1999) 133-143
46. Kunz D., Erker G., Fröhlich R., and Kehr G. Eur. J. Inorg. Chem. (2000) 409-416
47. Kunz D., Erker G., Fröhlich R., and Kehr G. Eur. J. Inorg. Chem. (2000) 409-416
48. Harmsen D., Erker G., Fröhlich R., and Kehr G. Eur. J. Inorg. Chem. (2002) 3156-3171
49. Hüerländer D., Kleigrewe N., Erker G., and Frölich R. Eur. J. Inorg. Chem. (2002) 2633-2642
50. Hill M., Kehr G., Erker G., Kataeva O., and Fröhlich R. Chem. Commun. (2004) 1020-1021
51. Kestel-Jakob A., and Alt H.G. Z. Naturforsch. B 62 (2007) 314-322
52. Schumann H., Heim A., Demstchuk J., and Mühle S.H. Organometallics 22 (2003) 118-128
53. Krska S.W., and Seyferth D. J. Am. Chem. Soc. 120 (1998) 3604-3612
54. Arteaga-Müller R., Sánchez-Nieves J., Royo P., and Mosquera M.E.G. Polyhedron 24 (2005) 1274-1279
55. Gambarotta S., Strologo S., Floriani C., Chiesi-Villa A., and Guastini C. Inorg. Chem. 24 (1985) 654-660
56. Durfee L.D., and Rothwell I.P. Chem. Rev. 88 (1988) 1059-1079
57. Erker G. Acc. Chem. Res. 17 (1984) 103-109
58. Erker G., and Rosenfeldt F. Angew. Chem. 90 (1978) 640-641
59. Erker G., and Rosenfeldt F. J. Organomet. Chem. 188 (1980) C1-C4
60. 4)] (1.50 g, 6.34 mmol) in thf (50 mL).
61. saint+ v7.12a, Area-Detector Integration Program, Bruker-Nonius AXS, Madison, Wisconsin, USA, 2004.
62. G.M. Sheldrick, sadabs Version 2004/1, A Program for Empirical Absorption Correction, University of Göttingen, Göttingen, Germany, 2004.
63. shelxtl-nt Version 6.12, Structure Determination Package, Bruker-Nonius AXS, Madison, Wisconsin, USA, 2001.