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note
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2Cl. Approaches for removing unwanted a-addition isomers from 1G-Vi and 2G-16Vi are the subject of a forthcoming publication: Krska, S. W.; Seyferth, D. Manuscript in preparation.
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59
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7144242480
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note
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k2 A special case of this formula, applicable to PAMAM dendrimers, may be found in ref 1.
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3I, which does not contain α-addition isomers.
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64
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7144224681
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note
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3Na are included in the Supporting Information; for mass spectra of other dendrimers, see ref 71.
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73
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7144219705
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note
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A good example of statistical distributions of lower molecular weight impurities may be found in the MALDI-TOF spectra of ref 23.
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74
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7144225725
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note
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70
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75
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7144225726
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note
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In addition, spectra of the second generation dendrimers each exhibited a sharp, relatively intense peak at approximately one-half the mass of the molecular ion, accompanied by fragment ions of the type discussed in the text. The m/z values of these peaks do not correlate with doubly charged ions or with any conceivable fragment ions or lower molecular weight impurities.
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76
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7144239766
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note
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59
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