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-1): 3043w, 2126s, 1600s, 1530m, 1491w, 1396m, 1065m, 817m. Synthesis of 2: 2 was prepared by the same procedure for synthesizing 1, but using 3-pyBpy in the place of
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-1): 3043w, 2126s, 1600s, 1530m, 1491w, 1396m, 1065m, 817m. Synthesis of 2: 2 was prepared by the same procedure for synthesizing 1, but using 3-pyBpy in the place of
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-1): 2926w, 2121s, 2074w, 1600s, 1534m, 1473w, 1387s, 813m.
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Data collection: Diffraction data were collected at 293(2) K with a Bruker-AXS SMART CCD area detector diffractometer using a Mo Ka radiation (λ, 0.71073 Å) and ω scan with a width of 0.3°. Multiscan absorptions were applied. The structures of 1 and 2 were solved by the direct methods and refined by full-matrix least-squares refinement on F2. All hydrogen atoms were included in calculated positions and reined with isotropic thermal parameters riding on those of the parent atoms and all non-hydrogen atoms were refined with anisotropic thermal parameters. Structure solutions and refinements were performed with the SHELXL-97 package. For all the compounds, the bridging cyanides indicate the disorders with respect to C and N termini and these disorders are treated by adopting 50% possibility of C and N occupancies at those sites. More details see the CIF files. Supporting Information
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2. All hydrogen atoms were included in calculated positions and reined with isotropic thermal parameters riding on those of the parent atoms and all non-hydrogen atoms were refined with anisotropic thermal parameters. Structure solutions and refinements were performed with the SHELXL-97 package. For all the compounds, the bridging cyanides indicate the disorders with respect to C and N termini and these disorders are treated by adopting 50% possibility of C and N occupancies at those sites. More details see the CIF files. Supporting Information.
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