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Volumn 9, Issue 3, 2009, Pages 1275-1277

Interpenetrating metal-organic frameworks assembled from polypyridine ligands and cyanocuprate catenations

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EID: 65249135448     PISSN: 15287483     EISSN: 15287505     Source Type: Journal    
DOI: 10.1021/cg801217j     Document Type: Article
Times cited : (55)

References (29)
  • 7
    • 33646720891 scopus 로고    scopus 로고
    • Chemistry of Transition Metal Cyanide Compounds: Modern Perspectives
    • John Wiley & Sons: New York
    • Dunbar, K. R.; Heintz, R. A. Chemistry of Transition Metal Cyanide Compounds: Modern Perspectives. In Progress in Inorganic Chemistry; John Wiley & Sons: New York, 2007; Vol. 45.
    • (2007) Progress in Inorganic Chemistry , vol.45
    • Dunbar, K.R.1    Heintz, R.A.2
  • 20
    • 65249104421 scopus 로고    scopus 로고
    • -1): 3043w, 2126s, 1600s, 1530m, 1491w, 1396m, 1065m, 817m. Synthesis of 2: 2 was prepared by the same procedure for synthesizing 1, but using 3-pyBpy in the place of
    • -1): 3043w, 2126s, 1600s, 1530m, 1491w, 1396m, 1065m, 817m. Synthesis of 2: 2 was prepared by the same procedure for synthesizing 1, but using 3-pyBpy in the place of
  • 21
    • 65249190066 scopus 로고    scopus 로고
    • -1): 2926w, 2121s, 2074w, 1600s, 1534m, 1473w, 1387s, 813m.
    • -1): 2926w, 2121s, 2074w, 1600s, 1534m, 1473w, 1387s, 813m.
  • 22
    • 65249110822 scopus 로고    scopus 로고
    • Data collection: Diffraction data were collected at 293(2) K with a Bruker-AXS SMART CCD area detector diffractometer using a Mo Ka radiation (λ, 0.71073 Å) and ω scan with a width of 0.3°. Multiscan absorptions were applied. The structures of 1 and 2 were solved by the direct methods and refined by full-matrix least-squares refinement on F2. All hydrogen atoms were included in calculated positions and reined with isotropic thermal parameters riding on those of the parent atoms and all non-hydrogen atoms were refined with anisotropic thermal parameters. Structure solutions and refinements were performed with the SHELXL-97 package. For all the compounds, the bridging cyanides indicate the disorders with respect to C and N termini and these disorders are treated by adopting 50% possibility of C and N occupancies at those sites. More details see the CIF files. Supporting Information
    • 2. All hydrogen atoms were included in calculated positions and reined with isotropic thermal parameters riding on those of the parent atoms and all non-hydrogen atoms were refined with anisotropic thermal parameters. Structure solutions and refinements were performed with the SHELXL-97 package. For all the compounds, the bridging cyanides indicate the disorders with respect to C and N termini and these disorders are treated by adopting 50% possibility of C and N occupancies at those sites. More details see the CIF files. Supporting Information.


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