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Volumn 11, Issue 8, 2009, Pages 1688-1692

Preparation of diphenyl phosphide and substituted phosphines using alkali metal in silica gel (M-SG)

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EID: 65249097355     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol900222v     Document Type: Article
Times cited : (8)

References (64)
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    • Phosphines and Phosphonium salts
    • The Royal Society of Chemistty: London
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    • (2001) Organophosphorous Chemistry , vol.31 , pp. 1-61
    • Allen, W.D.1
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    • Layman, W. J., Jr.; Welsh, G. W. Production of High Purity Alkali Metal Diphosphide and Cycloalkyldiarylphosphines U.S. Patent 5,866,720, Feb 2, 1999.
    • Layman, W. J., Jr.; Welsh, G. W. Production of High Purity Alkali Metal Diphosphide and Cycloalkyldiarylphosphines U.S. Patent 5,866,720, Feb 2, 1999.
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  • 37
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    • SiGNa Chemistry has developed three categories of alkali metal- nanostructured silica materials (M-SG): stage 0 materials are strongly reducing pyrophoric powders; stage I materials in dry air are nonpyrophoric, free-flowing black powders with reactivity equivalent to neat alkali metals; and stage II is less reducing but reacts with water to produce hydrogen at pressures from ambient to several thousand psi. All three categories of M-SG, with different metals and metal alloys absorbed, are available commercially.
    • SiGNa Chemistry has developed three categories of alkali metal- nanostructured silica materials (M-SG): stage 0 materials are strongly reducing pyrophoric powders; stage I materials in dry air are nonpyrophoric, free-flowing black powders with reactivity equivalent to neat alkali metals; and stage II is less reducing but reacts with water to produce hydrogen at pressures from ambient to several thousand psi. All three categories of M-SG, with different metals and metal alloys absorbed, are available commercially.
  • 41
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    • For a detailed procedure, refer to the Supporting Information
    • For a detailed procedure, refer to the Supporting Information.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.