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Volumn 79, Issue 12, 2009, Pages

Size-dependent magnetic spin and orbital moments of Fe nanoparticles deposited onto Co/W(110)

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EID: 65249097198     PISSN: 10980121     EISSN: 1550235X     Source Type: Journal    
DOI: 10.1103/PhysRevB.79.125423     Document Type: Article
Times cited : (38)

References (67)
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    • For sum-rule application, a steplike continuum contribution is subtracted from the averaged spectra (dotted gray line in the left part of Fig. 4) and a bulklike number of 3d holes (nh =3.49) is assumed (Ref.).
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    • Please note that magnetic orbital moments are underestimated by relativistic density-functional theory (Ref.). However, it has been shown that including a so-called orbital polarization (OP) term in respective calculations allows one to reproduce experimental bulk and surface data very well (Ref.). Our model calculations thus rely on values that take the OP term into account. A common result of surface magnetism theory is that the most significant enhancement of the orbital moment is restricted to the uppermost surface layer. Accordingly, our model considers only an enhancement in the outermost layer of the nanoparticles.
    • Please note that magnetic orbital moments are underestimated by relativistic density-functional theory (Ref.). However, it has been shown that including a so-called orbital polarization (OP) term in respective calculations allows one to reproduce experimental bulk and surface data very well (Ref.). Our model calculations thus rely on values that take the OP term into account. A common result of surface magnetism theory is that the most significant enhancement of the orbital moment is restricted to the uppermost surface layer. Accordingly, our model considers only an enhancement in the outermost layer of the nanoparticles.
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    • The actual strain will certainly depend on the materials being combined as well as on the orientation of the particles with respect to the substrate. Thus, the HRTEM investigations on Fe nanoparticles embedded in Al being presented in Sec. 3 do not allow one to draw conclusions on the strain profile of Fe particles supported by a Co/W(110) substrate.
    • The actual strain will certainly depend on the materials being combined as well as on the orientation of the particles with respect to the substrate. Thus, the HRTEM investigations on Fe nanoparticles embedded in Al being presented in Sec. 3 do not allow one to draw conclusions on the strain profile of Fe particles supported by a Co/W(110) substrate.


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