Understanding the regio- and chemoselective polar [3+2] cycloaddition of the Padwa carbonyl ylides with α-methylene ketones. A DFT study

Tetrahedron

Volumn 65, Issue 24, 2009, Pages 4644-4651

  Benchouk, Wafaa ^a   Mekelleche, Sidi Mohamed ^a   Aurell, Maria José ^b   Domingo, Luis Ramón ^b  

^a UNIVERSITY OF TLEMCEN   (Algeria)

^b UNIVERSITY OF VALENCIA   (Spain)

Author keywords

Density functional theory; Electron localization function; Electrophilicity; Nucleophilicity; Padwa carbonyl ylides; Polar 3+2 cycloadditions

Indexed keywords

ALPHA METHYLENE KETONE; CARBENE; CARBONYL DERIVATIVE; CARBONYL YLIDE; KETONE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CYCLOADDITION; DENSITY FUNCTIONAL THEORY; PRIORITY JOURNAL; QUANTUM YIELD; REACTION ANALYSIS; STEREOCHEMISTRY; STEREOISOMERISM; THERMODYNAMICS;

EID: 65149090081     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tet.2009.04.033     Document Type: Article

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