Effects and kinetics of a novel temperature cycling treatment on the N-deacetylation of chitin in alkaline solution

Carbohydrate Polymers

Volumn 77, Issue 1, 2009, Pages 110-117

  Liu, T G ^a,c   Li, B ^a,b   Huang, W ^a   Lv, B ^a   Chen, J ^a   Zhang, J X ^a   Zhu, L P ^a  

^a HUAZHONG AGRICULTURAL UNIVERSITY   (China)

^b NINGBO UNIVERSITY   (China)

^c CHIZHOU UNIVERSITY   (China)

Author keywords

Chitin; Chitosan; N deacetylation; Pseudo first order kinetics; Temperature cycling treatment

Indexed keywords

ALKALINE SOLUTIONS; APPARENT ACTIVATION ENERGIES; APPARENT RATE CONSTANTS; COLD-TREATMENT TEMPERATURES; EFFECTS OF TEMPERATURES; FREEZING TREATMENTS; HEAT-TREATMENT; N-DEACETYLATION; NAOH SOLUTIONS; PRE-TREATMENT METHODS; PSEUDO-FIRST-ORDER KINETICS; REACTION PROCESS; REACTION TIME; SHRIMP CHITINS; TEMPERATURE CYCLING TREATMENT; TEMPERATURE RANGES;

ACETYLATION; ACTIVATION ENERGY; CHITOSAN; HEAT TREATING FURNACES; RATE CONSTANTS; SUGAR (SUCROSE); TEMPERATURE; THERMAL EFFECTS;

CHITIN;

DECAPODA (CRUSTACEA);

EID: 64749099204     PISSN: 01448617     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.carbpol.2008.12.006     Document Type: Article

References (31)

1. Baxter S., Zivanovic S., and Weiss J. Molecular weight and degree of acetylation of high-intensity ultrasonicated chitosan. Food Hydrocolloids 19 (2005) 821-830
2. Brugnerotto J., Lizardi J., Goycoolea F.M., Argüelles-Monal W., Desbrières J., and Rinaudo M. An infrared investigation in relation with chitin and chitosan characterization. Polymer 42 (2001) 3569-3580
3. Castelli A., Bergamasco L., Beltrame P.L., and Focher B. Some insights into the kinetics of non-conventional alkaline deacetylation of chitin. In: Domard A., Jeuniaux C., Muzzarelli R., and Roberts G. (Eds). Advances in chitin science. Vol. I (1996), Jacques Andre, Lyon 198-203
4. Chae S.Y., Jang M.Y., and Nah J.W. Influence of molecular weight on oral absorption of water soluble chitosans. Journal of Controlled Release 102 (2005) 383-394
5. Chang, C. L., (1996). Effect of shear force, ultrasonic wave or both on the physicochemical property of chitosan and its application on the preparation of water-soluble chitosan. Master thesis, Graduate Institute of Aquatic Food Science, National Ocean University, Taiwan.
6. Chang K.L.B., Tsai G., Lee J., and Fu W.-R. Heterogenous N-deacetylation of chitin in alkaline solution. Carbohydrate Research 303 (1997) 327-332
7. Chen B.R. Studies on kinetics of deacetylation of chitin in heterogeneous alkaline solution. Chemical Research in Chinese Universities 13 7 (1992) 1008-1009
8. Chen Z., and Guo S. An improved method for the determination of the amino content of chitosan by alkalimetriy. Chinese Chemical Society 10 (1990) 42-43
9. Cho Y.W., Jang J., Park C.R., and Ko S.W. Preparation and solubility in acid and water of partially deacetylated chitins. Biomacromolecules 1 (2000) 609-614
10. Chung Y., Kuo C., and Chen C. Preparation and important functional properties of water-soluble chitosan produced through Maillard reaction. Bioresource Technology 96 (2005) 1473-1482
11. Dong Y.M., Wu Y.S., Wang J.W., and Wang M. Influence of degree of molar etherification on critical liquid crystal behavior of hydroxypropyl chitosan. European Polymer Journal 37 (2001) 1713-1720
12. Duarte M.L., Ferreira M.C., Marvao M.R., and Rocha J. An optimised method to determine the degree of acetylation of chitin and chitosan by FTIR spectroscopy. International Journal of Biological Macromolecules 31 (2002) 1-8
13. Feng F., Liu Y., and Hu K. Influence of alkali-freezing treatment on the solid state structure of chitin. Carbohydrate Research 339 (2004) 2321-2324
14. Focher B., Beltranme P.L., Naggi A., and Torri G. Alkaline N-deacetylation of enhanced by flash treatments: reaction kinetics and structure modifications. Carbohydrate Polymers 12 (1990) 405-418
15. Gu B., Wang Q., Liu X., and Xia W. An improved method for the determination of the amino content of chitosan. Journal of East China University of Science and Technology 29 3 (2003) 317-319
16. Holme K.R., and Perlin A.S. Chitosan N-sulfate: a water-soluble polyelectrolyte. Carbohydrate Research 302 1 (1997) 7-12
17. Je J.Y., Cho Y.S., and Kim S.K. Cytotoxic activities of water-soluble chitosan derivatives with different degree of deacetylation. Bioorganic & Medicinal Chemistry Letters 16 (2006) 2122-2126
18. Koide S. Chitin-chitosan: properties, benefits, and, risks. Nutrition-research 18 6 (1998) 1091-1101
19. Kurita K., Kamiya M., and Nishimura S. Solubilization of a rigid polysaccharide: controlled partial N-acetylation of chitosan to develop solubility. Carbohydrate Polymers 16 1 (1991) 83-88
20. Methacanona P., Prasitsilpa M., Pothsreea T., and Pattaraarchachaib J. Heterogeneous N-deacetylation of squid chitin in alkaline solution. Carbohydrate Polymers 52 (2003) 119-123
21. Rege P.R., and Block L.H. Chitosan processing: influence of process parameters during acidic and alkaline hydrolysis and effect of the processing sequence on the resultant chitosan's properties. Carbohydrate Research 321 (1999) 235-245
22. Sandford P.A. Chitosan: commercial uses and potential application. In: Skjak G., Anthonsen T., and Sandford P. (Eds). Chitin and chitosan: Sources, chemistry, biochemistry, physical properties and applications (1988), Elsevier, New York 51-69
23. Sannan T., Kurita K., and Iwakura Y. Solubility change by alkaline treatment and film casting. Die Makromoleculare Chemie 176 4 (1975) 1191-1195
24. Sannan T., Kurita K., and Iwakura Y. Effect of deacetylation on solubility. Die Makromoleculare Chemie 177 12 (1976) 3589-3593
25. Sannan T., Kurita K., and Iwakura Y. Kinetics of deacetylation reaction. Polymer 9 6 (1977) 649-651
26. Shigemasa Y., Matsuura H., Sashiwa H., and Saimoto H. Evaluation of different absorbance ratios from infrared spectroscopy for analyzing the degree of deacetylation in chitin. International Journal of Biological Macromolecules 18 (1996) 237-242
27. Tan S.C., Khor E., Tan T.K., and Wong S.M. The degree of deacetylation of chitosan: Advocating the first derivative UV-spectrophotometry method of determination. Talanta 45 (1998) 713-719
28. Tokura S., and Tamura H. O-Carboxymethyl-chitin concentration in granulocytes during bone repair. Biomacromolecules 2 2 (2001) 417-421
29. Tolaimate A., Desbrieres J., Rhazi M., Alagui A., Vicendon M., and Vottero P. On the influence of deacetylation process on the physicochemical characteristics of chitosan from squid chitin. Polymer 41 (2000) 2463-2469
30. Wang T., Turhan M., and Gunasekaran S. Selected properties of pH-sensitive, biodegradable chitosan-poly(vinyl alcohol) hydrogel. Polymer International 53 (2004) 911-918
31. Wu X., Zeng Q., Zeng F., and Zhang L. A discussion on determination of the deacetylation degree of chitosan by alkali titration method. Guangzhou Food Scicence and Technology 20 4 (2004) 96-97