Photooxidation of leaf-wound oxygenated compounds, 1-penten-3-ol, (z)-3-hexen-1-ol, and 1-penten-3-one, initiated by OH radicals and sunlight

Environmental Science and Technology

Volumn 43, Issue 6, 2009, Pages 1831-1837

  Jiménez, Elena ^a   Lanza, Beatriz ^a   Antiñolo, María ^a   Albaladejo, Jose ^a  

^a UNIVERSITY OF CASTILLA LA MANCHA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ARRHENIUS EXPRESSIONS; EXPERIMENTAL EVIDENCES; GAS-PHASE; GAS-PHASE REACTIONS; KINETIC STUDIES; OH RADICALS; OXYGENATED COMPOUNDS; RATE COEFFICIENTS; REMOVAL PROCESS; TROPOSPHERIC SINKS; UV-VISIBLE SPECTROSCOPIES; VINYL KETONES; WAVELENGTH DEPENDENCES;

ACTINIDES; ENVIRONMENTAL IMPACT; FREE RADICALS; KETONES; PHASE INTERFACES; PHOTOLYSIS; PHOTOOXIDATION; TROPOSPHERE; ULTRAVIOLET SPECTROSCOPY;

GAS ABSORPTION;

1 PENTEN 3 OL; 1 PENTEN 3 ONE; 3 HEXEN 1 OL; ETHYL VINYL KETONE; HYDROXYL RADICAL; KETONE; NITRATE; UNCLASSIFIED DRUG;

ABSORPTION; HYDROXYL RADICAL; LIGHT EFFECT; OXYGEN; PHOTOLYSIS; PHOTOOXIDATION; TROPOSPHERE;

ARTICLE; PHOTOLYSIS; PHOTOOXIDATION; SPECTRAL SENSITIVITY; SUNLIGHT; TROPOSPHERE; ULTRAVIOLET SPECTROSCOPY;

HEXANOLS; HYDROXYL RADICAL; LIGHT; OXIDATION-REDUCTION; PENTANOLS; PENTANONES; PHOTOLYSIS; PLANT LEAVES;

EID: 64549107488     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/es8027814     Document Type: Article

References (42)

1. Kesselmeier, J.; Staudt, M. Biogenic volatile organic compounds (VOC): An overview on emission, physiology and ecology. J. Atmos. Chem. 1999, 33, 23-88.
2. Fuentes, J. D.; Lerdau, M.; Atkinson, R.; Baldocchi, D.; Botten-heim, J. W.; Ciccioli, P.; Lamb, B.; Geron, C.; Gu, L.; Guenther, A.; Sharkey, T. D.; Stockwell, W. Biogenic hydrocarbons in the atmospheric boundary layer: A. review. Bull. Am. Meteorol. Soc. 2000, 153, 7-1575.
3. Guenther, A.; Zimmerman, P.; Harley, P.; Monson, R.; Fall, R. Isoprene and monoterpene emission rate variability: Model evaluation and sensitivity analysis. J. Geophys. Res. 1993, 98, 12609-12617.
4. Konig, G.; Brunda, M.; Puxbaum, H.; Hewitt, C. N.; Duckham, S. C.; Rudolph, J. Relative contribution of oxygenated hydrocarbons to the total biogenic VOC emissions of selected mid-European agricultural and natural plant species. Atmos. Environ. 1995, 29861-874.
5. Fukui, Y.; Doskey, P. V. An enclosure technique for measuring nonmethane organic compounds emissions from grasslands. J. Environ. Qual. 1996, 25, 601-610.
6. De Gouw, J. A.; Howard, C. J.; Custer, T. G.; Fall, R. Emissions of volatile organic compounds from cut grass and clover are enhanced during the drying process. Geophys. Res. Lett. 1999, 26, 811-814.
7. Zhang, Q. H.; Birgersson, G.; Zhu, J.; Löfstedt, C.; Löfqvist, J.; Schlyter, F. Leaf volatiles from nonhost deciduous trees: variation by tree species, season and temperature, and electrophysiological activity in Ips typographus. J. Chem. Ecol. 1999, 25, 1923-1943.
8. Heiden, A. C.; Kobel, K.; Langebartels, C.; Schuh-Thomas, G.; Wildt, J. Emissions of oxygenated volatile organic compounds from plants- part I: Emissions from lipoxygenase activity. J. Atmos. Chem. 2003, 45, 143-172.
9. 5 VOCs: release from leaves after freeze-thaw wounding and occurrence in air at a high mountain observatory. Atmos. Environ. 2001, 35, 3905-3916.
10. Karl, T.; Guenther, A.; Jordan, A.; Fall, R.; Lindinger, W. Eddy covariance measurement of biogenic oxygenated VOC emissions from hay harvesting. Atmos. Environ. 2001, 35, 491-495.
11. Karl, T.; Fall, R.; Jordan, A.; Lindinger, W. On-line analysis of reactive VOCs from urban lawn mowing. Environ. Sci. Technol. 2001, 35, 2926-2931.
12. Olofsson, M.; Ek-Olausson, B.; Ljungstrom, E.; Langer, S. Flux of organic compounds from grass measured by relaxed eddy accumulation technique. J. Environ. Monit. 2003, 5, 963-970.
13. Grosjean, D.; Grosjean, E.; Williams, E. L. Rate constants for the gas-phase reactions of ozone with unsaturated alcohols, esters, and carbonyls. Int. J. Chem. Kinet. 1993, 25, 783-794.
14. 3 reactions. Int. J. Chem. Kinet. 1995, 27, 941-955.
15. Grosjean, E.; Grosjean, D. Rate constants for the gas-phase reactions of ozone with unsaturated aliphatic alcohols. Int. J. Chem. Kinet. 1994, 26, 1185-1191.
16. 5 with stress-induced plant emissions. Atmos. Environ. 2007, 4, 1652-1662.
17. 5 with (Z)-hex-4-en-1-ol, (Z)-hex-3-en-1-ol ('leaf alcohol'), (E)-hex-3-en-1-ol, (Z)-hex-2-en-1-ol and (E)-hex-2-en-1-ol. Phys. Chem. Chem. Phys. 2006, 8, 354-363.
18. 3 with the man-made emissions 2-methylpent-2-ene, (Z)-3-methylpent-2-ene, ethyl vinyl ether, and the stress-induced plant emission ethyl vinyl ketone. Atmos. Environ. 2006, 40, 786-792.
19. Orlando, J. J.; Tyndall, G. S.; Ceazan, N. Rate coefficients and product yields from reaction of OH with 1-penten-3-ol, (Z)-2-penten-1-ol, and allyl alcohol (2-propen-1-ol). J. Phys. Chem. A 2001, 105, 3564-3569.
20. Jiménez, E.; Lanza, B.; Martínez, E.; Albaladejo, J. Daytime tropospheric loss of hexanal and trans-2-hexenal: OH kinetics and UV photolysis. Atmos. Chem. Phys. 2007, 7, 1565-1574.
21. Jiménez, E.; Lanza, B.; Garzón, A.; Ballesteros, B.; Albaladejo, J. Atmospheric degradation of 2-butanol, 2-methyl-2-butanol, and 2,3-dimethyl-2-butanol: OH kinetics and UV absorption cross sections. J. Phys. Chem. A 2005, 109, 10903-10909.
22. 5-aldehydes in the actinic region. Chem. Phys. Lett. 2008, 454, 184-189.
23. Jiménez, E.; Ballesteros, B.; Martínez, E.; Albaladejo, J. Tropospheric Reaction of OH with selected linear ketones: kinetic studies between 228 and 405 K. Environ. Sci. Technol. 2005, 39, 814-820.
24. Calvert, J. G.; Pitts, J. N. Photochemistry; John Wiley and Sons: New York, 1967.
25. Madronich, S.; Flocke, S. J. The role of solar radiation in atmospheric chemistry Handbook of Environmental Chemistry; Boule, P., Ed.; Springer-Verlag: Heidelberg, 1999.
26. Gierczak, T.; Burkholder, J. B.; Talukdar, R. K.; Mellouki, A.; Barone, S. B.; Ravishankara, A. R. Atmospheric fate of methyl vinyl ketone and methacrolein. J. Photochem. Photobiol., A 1997, 110, 1-10.
27. Raber, W. H.; Moortgat, G. K. Progress and Problems in Atmospheric Chemistry; Barker, J., Ed.; World Scientific Publ. Co.: Singapore, 1996; pp 318-373.
28. x budget. Faraday Discuss. 2005, 130, 73-88.
29. Kwok, E. S. C.; Atkinson, R. Estimation of hydroxyl radical reaction rate constants for gas-phase organic compounds using a structure-reactivity relationship. An update. Atmos. Environ. 1995, 29, 1685-1695.
30. 3P) with unsaturated alcohols and ethers: Correlations and structure-activity relations (SARs). Atmos. Environ. 2008, 42, 3018-3034.
31. Grosjean, D.; Grosjean, E.; Williams, E. L. Atmospheric chemistry of unsaturated alcohols. Environ. Sci. Technol. 1993, 27, 2478-2485.
32. 3 with α,β-unsaturated esters and ketones: Structure-activity relations (SARs). Atmos. Environ. 2007, 41, 1792-1802.
33. 3. Atmos. Environ. 1997, 31, 3551-3560.
34. x. Int. J. Chem. Kinet. 1989, 21, 1141-1152.
35. Smith, I. W. M.; Ravishankara, A. R. Role of hydrogen-bonded intermediates in the bimolecular reactions of the hydroxyl radical. J. Phys. Chem. A 2002, 106, 4798-4807.
36. x. Atmos. Environ. 2000, 34, 2063-2101.
37. Seinfeld, J. H.; Pandis, S. N. Atmospheric Chemistry and Physics: From Air Pollution to Climate Change; John Wiley and Sons: New York, 1998.
38. Kuhlmann R. Ph.D. dissertation. University of Mainz (Germany), 2001. Available at http://www.mpch-mainz.mpg.de/∼kuhl-mann/rvkdisshtml/node3.html.
39. Agencia Estatal de Meteorología. Ministerio de Medio Ambiente y Medio Rural y Marino. Available at http://www.aemet.es.
40. Sander, R. Compilation of Henry's law constants for inorganic and organic species of potential importance in environmental chemistry, 1999. Available at http://www.henrys-law.org.
41. Lide, D. R., Ed. CRC Handbook of Chemistry and Physics (Internet Version 2005); CRC Press: Boca Raton, FL, 2005. Available at http://www.hbcpnetbase.com.
42. Gelencsér, A.; Varga, Z. Evaluation of the atmospheric significance of multiphase reactions in atmospheric secondary organic aerosol formation. Atmos. Chem. Phys. 2005, 5, 2823-2831.