Role of hydrogen-bonded intermediates in the bimolecular reactions of the hydroxyl radical

Journal of Physical Chemistry A

Volumn 106, Issue 19, 2002, Pages 4798-4807

  Smith, Ian W M ^a   Ravishankara, A R ^b,c  

^a UNIVERSITY OF BIRMINGHAM   (United Kingdom)

^b NOAA EARTH SYSTEM RESEARCH LABORATORY   (United States)

^c UNIVERSITY OF COLORADO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BIMOLECULAR REACTIONS; ELECTRIC DIPOLE MOMENT; GAS PHASE REACTIONS; HYDROGEN BONDED INTERMEDIATES; HYDROGEN HALIDES; HYDROXYL RADICAL; RATE COEFFICIENTS;

ALDEHYDES; CARBON MONOXIDE; CARBOXYLIC ACIDS; ELECTRIC PROPERTIES; HYDROGEN BONDS; KETONES; MOLECULAR DYNAMICS; NITRIC ACID; PARAFFINS; RATE CONSTANTS;

FREE RADICALS;

EID: 0037117935     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp014234w     Document Type: Article

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80. 2A″). At least for rigid complexes, this would mean that reaction on one surface would be much favored over that on the other. However, given the nonrigidity of the complexes and the energy that is released as the complex form from reagents, such differences between reaction on the two surfaces are likely to be reduced in practice. These effects are therefore ignored in the discussion in this section.