Products of the gas-phase reactions of cis-3-hexen-1-ol with OH radicals and O3

Atmospheric Environment

Volumn 31, Issue 21, 1997, Pages 3551-3560

  Aschmann, Sara M ^a   Shu, Yonghui ^a   Arey, Janet ^a   Atkinson, Roger ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Atmospheric reactions; cis 3 Hexen 1 ol; Hydroxyl radical; Ozone; Reaction products

Indexed keywords

FOURIER TRANSFORM INFRARED SPECTROSCOPY; FREE RADICAL REACTIONS; GAS CHROMATOGRAPHY; IONIZATION OF GASES; MASS SPECTROMETRY; NITRATES; NITROGEN OXIDES; OZONE; REACTION KINETICS;

ATMOSPHERIC REACTIONS; FLAME IONIZATION DETECTION (FID); HYDROXY RADICALS;

ATMOSPHERIC CHEMISTRY;

HYDROXYL RADICAL; OZONE; PROPIONALDEHYDE;

BIOGENIC EMISSION; GAS PHASE REACTION; HYDROXYL RADICAL;

AIR SAMPLING; ARTICLE; GAS CHROMATOGRAPHY; INFRARED SPECTROSCOPY; MOLECULAR WEIGHT; PHASE TRANSITION; PRIORITY JOURNAL; REACTION ANALYSIS; TANDEM MASS SPECTROMETRY;

EID: 0031282620     PISSN: 13522310     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1352-2310(97)00205-7     Document Type: Article

References (25)

1. Arey, J., Winer, A. M., Atkinson, R., Aschmann, S. M., Long, W. D. and Morrison, C. L. (1991) The emission of (Z)-3-hexen-1-ol, (Z)-3-hexenylacetate and other oxygenated hydrocarbons from agricultural plant species. Atmospheric Environment 25A, 1063-1075.
2. Atkinson, R. (1994) Gas-phase tropospheric chemistry of organic compounds. Journal of Physical Chemistry Ref. Data Monograph 2, 1-216.
3. Atkinson, R. (1997) Atmospheric reactions of alkoxy and β-hydroxyalkoxy radicals. International Journal of Chemical Kinetics 29, 99-111.
4. Atkinson, R., Carter, W. P. L., Winer, A. M. and Pitts, J. N. Jr. (1981) An experimental protocol for the determination of OH radical rate constants with organics using methyl nitrite photolysis as an OH radical source. Journal of the Air Pollutution Control Association 31, 1090-1092.
5. 8 n-alkanes. Journal of Physical Chemistry 86, 4563-4569.
6. 3 with a series of alkenes under atmospheric conditions. Environmental Science and Technology 27, 1357-1363.
7. 3 reactions. International Journal of Chemical Kinetics 27, 941-955.
8. Atkinson, R., Kwok, E. S. C., Arey, J. and Aschmann, S. M. (1995b) Reactions of alkoxy radicals in the atmosphere. Faraday Discussions of the Chemical Society 100, 23-37.
9. 3 with alkenes. Environment Science and Technology 29, 1860-1866.
10. Buttery, R. G., Ling, L. C. and Wellso, S. G. (1982) Oat leaf volatiles: possible insect attractants. Journal of Agricultural and Food Chemistry 30, 791-792.
11. Buttery, R. G., Xu, C. and Ling, L. C. (1985) Volatile components of wheat leaves (and stems): possible insect attractants. Journal Agricultural and Food Chemistry 33, 115-117.
12. Grosjean, D., Grosjean, E. and Williams, E. L. II (1993a) Rate constants for the gas-phase reactions of ozone with unsaturated alcohols, esters, and carbonyls. International Journal of Chemical Kinetics 25, 783-794.
13. Grosjean, D., Williams, E. L. II and Grosjean, E. (1993b) A biogenic precursor of peroxypropionyl nitrate: Atmospheric oxidation of cis-3-hexen-1-ol. Environmental Science and Technology 27, 979-981.
14. Grosjean, D., Grosjean, E. and Williams, E. L. II (1993c) Atmospheric chemistry of unsaturated alcohols. Environmental Science and Technology 27, 2478-2485.
15. Isidorov, V. A., Zenkevich, I. G. and Ioffe, B. V. (1985) Volatile organic compounds in the atmosphere of forests. Atmospheric Environment 19, 1-8.
16. König, G., Brunda, M., Puxbaum, H., Hewitt, C. N., Duckham, S. C. and Rudolph, J. (1995) Relative contribution of oxygenated hydrocarbons to the total biogenic VOC emissions of selected mid-European agricultural and natural plant species. Atmospheric Environment 29, 861-874.
17. Kwok, E. S. C., Atkinson, R. and Arey, J. (1995) Observation of hydroxycarbonyls from the OH radical-initiated reaction of isoprene. Environmental Science and Technology 29, 2467-2469.
18. 8 n-alkanes. Journal of Physical Chemistry 100, 214-219.
19. 8 1-alkenes. Environmental Science and Technology 30, 1048-1052.
20. Kwok, E. S. C. and Arey, J. (1997) Dimer formation in the atmospheric pressure ionization tandem mass spectrometer (API-MS/MS) for product studies of atmospherically important reactions of hydrocarbons (in preparation).
21. Lwande, W. and Bentley, M. D. (1987) Volatiles of Sorghum bicolor seedlings. Journal of Natural Products 50, 950-952.
22. Ohta K. (1984) Emission of hexenol from higher plants. Geochemical Journal 18, 135-141.
23. Scanlon, J. T. and Willis, D. E. (1985) Calculation of flame ionization detector relative response factors using the effective carbon number concept. Journal of Chromatographic Science 23, 333-340.
24. Schulting, F. L., Meyer, G. M. and van Aalst, R. M. (1980) Emissie van koolwaterstoffen door vegetatie en de bijdrage aan de luchtverontreiniging in Nederland. TNO Rapport CMP 80/16, Delft, The Netherlands, November 1.
25. Sharkey, T. D. (1996) Emission of low molecular mass hydrocarbons from plants. Trends in Plant Science 1, 78-82.