Surface segregation of counterions in ionomer films

Macromolecules

Volumn 41, Issue 23, 2008, Pages 9299-9305

  Walters, Russel M ^a,c   Taubert, Andreas ^a,d   Kim, Joon Seop ^b   Winey, Karen I ^a   Composto, Russell J ^a  

^a UNIVERSITY OF PENNSYLVANIA   (United States)

^b Chosun University   (South Korea)

^c JOHNSON AND JOHNSON   (United States)

^d UNIVERSITY OF POTSDAM   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CATION MOBILITIES; CONCENTRATION GRADIENTS; COUNTER-IONS; DIVALENT CATIONS; DRIVING FORCES; ELEVATED TEMPERATURES; HIGH TEMPERATURES; HIGHER TEMPERATURES; IONOMER FILMS; LONE PAIRS; METHACRYLIC ACIDS; RUTHERFORD BACKSCATTERING SPECTROMETRIES; SCANNING FORCE MICROSCOPIES; SPIN-CAST FILMS; STYRENE MONOMERS; SURFACE CONCENTRATIONS; SURFACE EXCESS; TRANSMISSION ELECTRONS; UNIFORM DISTRIBUTIONS; VESICULAR AGGREGATES;

ACIDS; AGGLOMERATION; CESIUM; CESIUM ALLOYS; CESIUM COMPOUNDS; IONOMERS; POLYMERS; POLYSTYRENES; POSITIVE IONS; RUTHERFORD BACKSCATTERING SPECTROSCOPY; SCANNING; SCANNING TUNNELING MICROSCOPY; SEGREGATION (METALLOGRAPHY); STYRENE;

SURFACE SEGREGATION;

EID: 64549103276     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma801756g     Document Type: Article

References (33)

1. Eisenberg, A.; Kim, J. S. Introduction to Ionomers; Wiley-Interscience: New York, 1998.
2. Van Alsten, J. G. Macromolecules 1996, 29, 2163-2168.
3. Kolbet, K. A.; Schweizer, K. S. Macromolecules 2000, 33, 14251442.
4. Colby, R. H.; Zheng, X.; Rafailovich, M. H.; Sokolov, J.; Peiffer, D. G.; Schwarz, S. A.; Strzhemechny, Y.; Nguyen, D. Phys. Rev. Lett. 1998, 81, 3876-3879.
5. Vanhoorne, P.; Register, R. A. Macromolecules 1996, 29, 598-604.
6. Vyprachticky, D.; Morawetz, H.; Fainzilberg, V. Macromolecules 1993, 26, 339-343.
7. Klein, R. J.; Zhang, S.; Dou, S.; Jones, B. H.; Colby, R. H.; Runt, J. J. CJhem. Phys. 2006, 124, 144903.
8. Zhang, S.; Dou, S.; Colby, R. H.; Runt, J. J. Non-Cryst. Solids 2005, 352, 2825-2830.
9. Kutsumizu, S.; Goto, M.; Yano, S.; Schlick, S. Macromolecules 2002, 35, 6298-6305.
10. Laurer, J.; Winey, K. Macromolecules 1998, 31, 9106-9108.
11. Benetatos, N. M.; Smith, B. W.; Heiney, P. A.; Winey, K. I. Macromolecules 2005, 38, 9251-9257.
12. Benetatos, N. M.; Heiney, P. A.; Winey, K. I. Macromolecules 2006, 39, 5174-5176.
13. Benetatos, N. M.; Chan, C. D.; Winey, K. I. Macromolecules 2007, 40, 1081-1088.
14. Benetatos, N. M.; Winey, K. I. J. Polym. Sci, Part B: Polym. Phys. 2005, 43, 3549-3554.
15. Benetatos, N. M.; Winey, K. I. Macromolecules 2007, 40, 3223-3228.
16. Batra, A.; Cohen, C; Kim, H.; Winey, K. I; Ando, N.; Gruner, S. M. Macromolecules 2006, 39, 1630-1638.
17. Kirkmeyer, B. P.; Taubert, A.; Kim, J. S.; Winey, K. I. Macromolecules 2002, 35, 2648-2653.
18. McLean, S. R.; Doyle, M.; Sauer, B. B. Macromolecules 2000, 33, 6541-6550.
19. Sauer, B. B.; McLean, S. R. Macromolecules 2000, 33, 7939-7949.
20. Composto, R. J.; Walters, R. M.; Genzer, J. Mater. Sci Rep. 2002, 38, 107-180.
21. Doolittle, R. L. Nucl, Instrum. Meth. B 1985, ,9, 344-351.
22. Tanaka, P. L.; Oldfield, S.; Neece, J. D.; Mullins, C. B.; Allen, D. T. Environ. Sci Technol. 2000, 34, 4470-4473.
23. Wingenter, O.; Sive, B.; Blake, N.; Blake, D.; Rowland, F. J. Geophysical Res. 2005, 110, D20308.
24. Chang, S.; Allen, D. T. Atoms; Environ. 2006, 40, 512-523.
25. Jones, R. A.; Kramer, E. J. Philos. Mag. B 1990, 62, 129.
26. Walters, R. Counterion Surface Segregation in Ionomer. Doctoral Thesis, University of Pennsylvania: Philadelphia, PA, 2003.
27. Doughery, D. A. Science 1996, 271, 163-168.
28. Sunner, J.; Nishizawa, K.; Kebarle, P. J.Phys. Chem. 1981, 85, 18141820.
29. Fujimura, M.; Hashimoto, T.; Kawai, H. Macromolecules 1982, 15, 136-144.
30. Yarusso, D. J.; Cooper, S. L. Macromolecules 1983, 16, 1871-1880.
31. Gebel, G.; Lambard, J. Macromolecules 1997, 30, 7914-7920.
32. Leibler, L.; Rubinstein, M.; Colby, R. H. Macromolecules 1991, 24, 4701-4712.
33. Handlin, D. L.; MacKnight, W. J.; Thomas, E. L. Macromolecules 1981, 14, 795-801.