Pervaporation of ethanol aqueous solution by polyphosphazene membranes: Effect of pendant groups

Separation and Purification Technology

Volumn 66, Issue 3, 2009, Pages 504-509

  Huang, Yawen ^a   Fu, Jianwei ^a   Pan, Yang ^a   Huang, Xiaobin ^a   Tang, Xiaozhen ^a  

^a SHANGHAI JIAO TONG UNIVERSITY   (China)

Author keywords

Hydrophobic; Pervaporation performance; Polyphosphazene; Solubility parameter

Indexed keywords

ETHANOL AQUEOUS SOLUTIONS; FILM-FORMING; HETEROPOLYMERS; HYDROPHOBIC; HYDROPHOBIC GROUPS; HYDROPHOBIC PROPERTIES; MEMBRANE SEPARATIONS; PENDANT GROUPS; PHOSPHAZENE; POLY-PHOSPHAZENE MEMBRANES; POLYMER MEMBRANES; POLYPHOSPHAZENE; SOLUBILITY PARAMETER;

BIOLOGICAL MATERIALS; ETHANOL; EVAPORATION; FUNCTIONAL POLYMERS; HYDROPHOBICITY; PERVAPORATION; SOLUBILITY; SORPTION; TERNARY SYSTEMS;

AMORPHOUS MATERIALS;

EID: 64449086233     PISSN: 13835866     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.seppur.2009.02.018     Document Type: Article

References (23)

1. O'Brien D.J., Roth L.H., and McAloon A.J. Ethanol production by continuous fermentation-pervaporation: a preliminary economic analysis. J. Membr. Sci. 166 (2000) 105-111
2. Luccio M.D., Borges C.P., and Alves T.L.M. Economic analysis of ethanol and fructose production by selective fermentation coupled to pervaporation: effect of membrane costs on process economics. Desalination 147 (2002) 161-166
3. Vane L.M. A review of pervaporation for product recovery from biomass fermentation processes. J. Chem. Technol. Biotechnol. 80 (2005) 603-629
4. Takegemi S., Yamada H., and Tusujii S. Pervaporation of ethanol/water mixtures using novel hydrophobic membranes containing polydimethylsiloxane. J. Membr. Sci. 75 (1992) 93-105
5. Li L., Xiao Z.Y., Tan S.J., Pa L., and Zhang Z.B. Composite PDMS membrane with high flux for the separation of organics from water by pervaporation. J. Membr. Sci. 243 (2004) 177-187
6. Xiangli F.J., Chen Y.W., Jin W.Q., and Xu N.P. Polydimethylsiloxane (PDMS)/ceramic composite membrane with high flux for pervaporation of ethanol-water mixtures. Ind. Eng. Chem. Res. 46 (2007) 2224-2230
7. Molina J.M., Vatai G., and Bekassy-Molnar E. Comparison of pervaporation of different alcohols from water on CMG-OM-010 and 1060-SULZER membranes. Desalination 149 (2002) 89-94
8. Ishihara K., Nagase Y., and Matsui K. Pervaporation of alcohol/water mixtures through poly[1-(trimethylsilyl)-1-propyne] membrane. Die Makromolekulare Chemie. Rapid Commun. 7 (1986) 43-46
9. Masuda T., Takatsuka M., Tang B.Z., and Higashimura T. Pervaporation of organic liquid-water mixtures through substituted polyacetylene membranes. J. Membr. Sci. 49 (1990) 69-83
10. Stern S.A., Mi Y., Yammamoto H., and Clair A.K.St. Structure/permeability relationships of polyimide membranes. Applications to the separation of gas mixtures. J. Polym. Sci: Part B: Polym. Phys. 27 (1989) 1887-1909
11. Miyata T., Nakanishi Y., and Uragami T. Ethanol permselectivity of poly(dimethylsiloxane) membranes controlled by simple surface modifications using polymer additives. Macromolecules 30 (1997) 5563-5565
12. Miyata J., Higuchi O.H., and Uragami T. Preparation of polydimethylsiloxane/polystyrene interpenetrating polymer network membranes and permeation of aqueous ethanol solutions through the membranes by pervaporation. J. Appl. Polym. Sci. 61 (1996) 1315-1324
13. Gleria M., and Jaeger R.D. Polyphosphazenes: a review. Top Curr. Chem. 250 (2005) 165-251
14. Orme C.J., Stewart F.F., Harrup M.K., McCoy J.D., and Weinkauf D.H. Pervaporation of water-dye, alcohol-dye, and water-alcohol mixtures using a polyphosphazene membrane. J. Membr. Sci. 197 (2002) 89-101
15. Stewart F.F., Harrup M.K., Luther T.A., Orme C.J., and Lash R.P. Formation of pervaporation membranes from polyphosphazenes having hydrophilic and hydrophobic pendant groups: synthesis and characterization. J. Appl. Polym. Sci. 80 (2001) 422-431
16. Roizard D., Clement R., Lochon P., Kerres J., and Eigenberger G. Synthesis, characterization and transport properties of a new siloxane-phosphazene copolymer. Extraction of n-butanol from water by pervaporation. J. Membr. Sci. 113 (1996) 151-160
17. 5. Chem. Eur. J. 9 (2003) 3833-3836
18. Xiao S., Huang R.Y.M., and Feng X. Preparation and properties of trimesoyl chloride crosslinked poly(vinyl alcohol) membranes for pervaporation dehydration of isopropanol. J. Membr. Sci. 286 (2006) 245-254
19. Huang S.C., Ball I.J., and Kaner R.B. Polyaniline membranes for pervaporation of carboxylic acids and water. Macromolecules 31 (1998) 5456-5464
20. Wu P., Brisdon B.J., England R., and Field R.W. Preparation of modified difunctional PDMS membranes and a comparative evaluation of their performance for the pervaporative recovery of p-cresol from aqueous solution. J. Membr. Sci. 206 (2002) 265-275
21. Kamaruddin H.D., and Koros W.J. Some observations about the application of Fick's first law for membrane separation of multicomponent mixtures. J. Membr. Sci. 135 (1997) 147-159
22. Van krevelen D.W. Properties of Polymers: Their Estimation and Correlation with Chemical Structure, Part □ (1997), Elsevier Science B.V., Amsterdam pp. 761-845
23. Shao P., and Huang R.Y.M. Polymeric membrane pervaporation. J. Membr. Sci. 287 (2007) 162-179