Polydimethylsiloxane (PDMS)/ceramic composite membrane with high flux for pervaporation of ethanol-water mixtures

Industrial and Engineering Chemistry Research

Volumn 46, Issue 7, 2007, Pages 2224-2230

  Fenjuan, Xiangli ^a   Yiwei, Chen ^a   Wanqin, Jin ^a   Nanping, Xu ^a  

^a NANJING TECH UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

BIOMASS; ETHANOL; PERVAPORATION; POLYDIMETHYLSILOXANE; POLYMERIC MEMBRANES; SCANNING ELECTRON MICROSCOPY; WATER;

ETHANOL CONCENTRATION; FOURIER TRANSFORM INFRARED-ATTENTUATED TOTAL REFLECTANCE (FTIR-ATR);

WATER TREATMENT;

BIOMASS; ETHANOL; PERVAPORATION; POLYDIMETHYLSILOXANE; POLYMERIC MEMBRANES; SCANNING ELECTRON MICROSCOPY; WATER; WATER TREATMENT;

EID: 34247159569     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie0610290     Document Type: Article

References (34)

1. Further, W. F. Production of fuel-grade ethanol by extractive distillation employing the salt effect. Sep. Purif. Methods 1993, 22, 1.
2. Nakao, S.-I.; Saitoh, F.; Asakura, T.; Toda, K.; Kimura, S. Continuous ethanol extraction by pervaporation from a membrane bioreactor. J. Membr. Sci. 1987, 30, 273.
3. Hickey, P. J.; Slater, C. S. Selective recovery of alcohols from fermentation broths by pervaporation. Sep. Purif. Methods 1990, 19, 93.
4. O'Brien, D. J.; Roth, L. H.; McAloon, A. J. Ethanol production by continuous fermentation-pervaporation: a preliminary economic analysis. J. Membr. Sci. 2000, 166, 105.
5. Ikegami, T.; Kitamoto, D.; Negishi, H.; Iwakabe, K.; Umura, T.; Sano, T.; Haraya, K.; Yanagishia, H. Reliable production of highly concentrated bioethanol by a conjunction of pervaporation using a silicone rubber sheet-covered silicalite membrane with adsorption process. J. Chem. Technol. Biotechnol. 2004, 79, 896.
6. Vane, L. M A review of pervaporation for product recovery from biomass fermentation processes. J. Chem. Technol. Biotechnol. 2005, 80, 603.
7. Okamoto, K.-I.; Butsuen, A.; Tsuru, S.; Nishioka, S.; Tanaka, K.; Kita, H.; Asakawa, S. Pervaporation of water-ethanol mixtures through polydimethyl-siloxane block-copolymer membranes. Polym. J. 1987, 19, 747.
8. Kashiwagi, T.; Okabe, K.; Okita, K. Separation of ethanol from ethanol/water mixtures by plasma-polymerized membranes from silicone compounds. J. Membr. Sci. 1986, 36, 353.
9. Blume, I.; Wijmans, J. G.; Baker, R. W. The separation of dissolved organics from water by pervaporation. J. Membr. Sci. 1990, 49, 253.
10. Takegemi, S.; Yamada, H.; Tusujii, S. Pervaporation of ethanol/water mixture using novel hydrophobic membrane containing polydimethylsiloxane. J. Membr. Sci. 1992, 75, 93.
11. Hickey, P. J.; Juricic, F. P.; Slater, C. S. The effect of process parameters on the pervaporation of alcohols through organophilic membranes. Sep. Sci. Technol. 1992, 27, 843.
12. Uragami, T.; Doi, T.; Miyata, T. Control of permselectivity with surface modifications of poly[1-(trimethylsilyl)-1-propyne] membranes. Int. J. Adhes. Adhes. 1999, 19, 405.
13. Gonzalez-Velasco, J. R.; Gonzalez-Marcos, J. A.; Lopez-Dehesa, C. Pervaporation of ethanol-water mixtures through poly(1-trimethylsilyl-1-propyne) (PTMSP) membranes. Desalination 2002, 149, 61.
14. Volkov, V. V.; Fadeev, A. G.; Khotimsky, V. S.; Litvinova, E. G.; Selinskaya. Y. A.; McMillan, J. D.; Kelley, S. S. Effects of synthesis conditions on the pervaporation properties of poly[1-(trimethylsilyl)-1-propyne] useful for membrane bioreactors. J. Appl. Polym. Sci. 2004, 91, 2271.
15. Ishibara, K.; Matsui, K. Pervaporation of ethanol-water mixture through composite membrane composed of styrene-fluoroalkyl acrylate graft copolymers and cross-linked polydimethylsiloxane membrane. J. Appl. Polym. Sci. 1987, 34, 437.
16. Nagase, Y.; Ishihara, K.; Matsui. K. Chemical modification of poly-(substituted-acetylene): II. Pervaporation of ethanol/water mixture through poly(1 -trimethylsilyl-1-propyne)/poly(dimethylsiloxane) graft copolymer membrane. J. Polym. Sci. 1990, 28, 377.
17. Aoki, T.; Yamagiwa, K.; Yoshino, E.; Oikawa, E. Temperature-sensitive ethanol permselectivity of poly(dimethylsiloxane) membrane by the modification of its surface with copoly(N-isopropylacrylamide/1H, 1H,-2H,2H-perfluorododecyl acrylate). Polymer 1993, 34, 1538.
18. Kang, Y. S; Shin, E. M.; Jung, B.; Kim, J.-J. Composite membranes of poly(1-trimethylsilyl-1-propyne) and poly(dimethyl siloxane) and their pervaporation properties for ethanol-water mixture. J. Polym. Sci. 1994, 53, 317.
19. Liang, L.; Ruckenstein, E. Pervaporation of ethanol-water mixtures through polydimethylsiloxane-polystyrene interpenetrating polymer network supported membranes. J. Membr. Sci. 1996, 114, 227.
20. Galindo, M. O.; Clar, A. I.; Miranda, I. A.; Greus, A. R. Characterization of poly(dimethylsiloxane)-poly(methyl hydrogen siloxane) composite membrane for organic water pervaporation separation. J. Appl. Polym. Sci. 2001, 81, 546.
21. Jia, M.-D.; Peinemann, K.-V.; Behling, R.-D. Preparation and characterization of thin-film zeolite-PDMS composite membranes. J. Membr. Sci. 1992, 73, 119.
22. Matsuda, H.; Yanagishita, H.; Negishi, H.; Kitamoto, D.; Ikegami, T.; Haraya, K.; Nakane, K.; Idemoto, Y.; Koura, N.; Sano, T. Improvement of ethanol selectivity of silicalite membrane in pervaporation by silicone rubber coating. J. Membr. Sci. 2002, 210, 433.
23. Chang, C.-L.; Chang, M.-S. Preparation of multi-layer silicone/PVDF composite membranes for pervaporation of ethanol aqueous solutions. J. Membr. Sci. 2004, 238, 117.
24. Li, L.; Xiao, Z. Y.; Tan, S. J.; Pu, L. Z.; Zhang, B. Composite PDMS membrane with high flux for the separation of organics from water by pervaporation. J. Membr. Sci. 2004, 243, 177.
25. Rezac, M. E.; Koros, W. J. Preparation of polymer-ceramic composite membranes with thin defect-free separating layers. J. Appl. Polym. Sci. 1992, 46, 1927.
26. Song, K. M.; Hong, W. H. Dehydration of ethanol and isopropanol using tubular type cellulose acetate membrane with ceramic support in pervaporation process. J. Membr. Sci. 1997, 123, 27.
27. Yoshida, W.; Cohen, Y. Ceramic-supported polymer membranes for pervaporation of binary organic/organic mixtures. J. Membr. Sci. 2003, 213, 145.
28. Peters, T. A.; Poeth, C. H. S.; Benes, N. E.; Buijs, H. C. W. M.; Vercauteren, F. F.; Keurentjes, J. T. F. Ceramic-supported thin PVA pervaporation membranes combining high flux and high selectivity; contradicting the flux-selectivity paradigm. J. Membr. Sci. 2006, 276, 42.
29. Baker, R. W. Membrane Transport Theory. In Membrane Technology and Applications; Wiley: Chichester, U.K., 2004.
30. Shah, D.; Kissick, K.; Ghorpade, A.; Hannah, R.; Bhattacharyya, D. Pervaporation of alcohol-water and dimethylformamide-water mixture using hydrophilic zeolite NaA membranes: mechanism and experimental results. J. Membr. Sci. 2000, 179, 185.
31. Hofmann, D.; Fritz, L.; Ulbrich, J.; Paul, D. Molecular modelling of amorphous membrane polymers. Polymer 1997, 38, 6145.
32. Feng, X.; Huang, R. Y. M. Estimation of activation energy for permeation in pervaporation processes. J. Membr. Sci. 1996, 118, 127.
33. Wijmans, J. G.; Baker, R. W. The solution-diffusion model: a review. J. Membr. Sci. 1995, 107, 1.
34. Vankelecom, I. F. J.; Moermans, B.; Verschueren, G.; Jacobs, P. A. Intrusion of PDMS top layers in porous supports. J. Membr. Sci. 1999, 158, 289.