On factors influencing insertion of allylic substrates in Pd-Caryl bonds

Inorganica Chimica Acta

Volumn 362, Issue 6, 2009, Pages 2015-2019

  Felice, Vincenzo De ^a   de Renzi, Augusto ^b   Fraldi, Natascia ^b   Panunzi, Barbara ^b  

^a UNIVERSITY OF MOLISE   (Italy)

^b UNIVERSITY OF NAPLES FEDERICO II   (Italy)

Author keywords

Allylic substrates; Insertion reactions; Palladium(II) aryl complexes

Indexed keywords

ARGON; PLATINUM COMPOUNDS;

1 ,10-PHENANTHROLINE; ALLYLIC SUBSTRATES; COORDINATING SOLVENTS; INSERTION REACTIONS; OXIDATIVE ADDITIONS; PRODUCTS OF REACTION; RELATIVE STABILITIES; SEQUENTIAL EQUILIBRIUM;

PALLADIUM COMPOUNDS;

EID: 64349098690     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ica.2008.09.027     Document Type: Article

References (19)

1. Heck R.F. Adv. Catal. 26 (1977) 323
2. Bouquillon S., Ganchegui B., Estrine B., Henin F., and Muzart J. J. Organomet. Chem. 634 (2001) 153
3. Calò V., Nacci A., Monopoli A., and Ferola V. J. Org. Chem. 72 (2007) 2596
4. Zhao H., Cai M., Hu R., and Song C. Synth. Commun. 31 (2001) 3665
5. Rathin J., Shubhankar S., and Jayanta R. Tetrahedron Lett. 49 (2008) 851
6. De Felice V., de Renzi A., Tesauro D., and Vitagliano A. Organometallics 11 (1992) 3669
7. De Felice V., Cucciolito M.E., de Renzi A., Ruffo F., and Tesauro D. J. Organomet. Chem. 493 (1994) 1
8. Hahn F.E., Jahnke M.C., and Pape T. Organometallics 25 (2006) 5927
9. Allowisng that heterogeneous platinum-prompted processes are under investigation, e.g.:. Kantam M.L., Roy M., Roy S., Subhas M.S., Sreedhar B., and Choudary B.M. Synlett 14 (2006) 2266
10. Kruis D., Markies B.A., Canty A.J., Boersma J., and Van Koten G. J. Organomet. Chem. 532 (1997) 235
11. Cucciolito M.E., de Renzi A., Giordano F., and Ruffo F. Organometallics 14 (1995) 5410
12. The mediocre stability of cationic aryl Pd(II) complexes (T. Yagyu, M. Hamada, K. Osakada, T. Yamamoto, Organometallics 20 (2001) 1087) is reasonably expected to be even lower if electron-donor inductive effect increases reactivity of the metal towards oxydative addition.
13. We recall that in water a 4.5 to 1 ratio was founded:. Didier V., and Belkacem N. Procedings of ESOC-1 and -2; First and second International Electronic Conference on Synthetic Organic Chemistry (1999) 30
14. Larock R.C., Leung W.J., and Stolz S. Tetrahedron Lett. 30 (1989) 6629
15. Macchioni A. Chem. Rev. 105 (2005) 2039
16. Lemkuhl H., Keil T., Benn R., Rufinska A., Kruger C., Poplawska J., and Bellenbaum M. Chem. Ber. 121 (1988) 1931
17. Fernandez-Rivas C., Cardenas D.J., Martin-Matute B., Monge A., Gutierrez-Puebla E., and Echavarren A.M. Organometallics 20 (2001) 2998
18. Bieg T., and Szeja W. J. Carbohydr. Chem. 4 (1985) 441
19. Larock R.C., and Baker B.E. Tetrahedron Lett. 29 (1988) 905