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Volumn 113, Issue 7, 2009, Pages 1199-1209

Dynamics of Si#H#Si bridges in agostically stabilized silylium ions

Author keywords

[No Author keywords available]

Indexed keywords

AGOSTIC INTERACTIONS; DFT CALCULATIONS; HYDRIDE TRANSFERS; INTERNAL ROTATIONS; NMR SPECTRUM; ROOM TEMPERATURES; SILYL GROUPS; VIBRATIONAL DYNAMICS;

EID: 63849191275     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp807603t     Document Type: Article
Times cited : (12)

References (81)
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    • 29Si isotopomer of 1 its signal would appear as a triplet (neglecting the H-H coupling to the Me group), whereas other Si-H signals would be doublets.
    • 29Si isotopomer of 1 its signal would appear as a triplet (neglecting the H-H coupling to the Me group), whereas other Si-H signals would be doublets.
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    • Only one of six silicon atoms in 1 would contribute to coupling with protons, and the average J(Si-H) should be reduced by a factor of 1/6. We thank R. Simionescu for the explanation of this spectral feature
    • Only one of six silicon atoms in 1 would contribute to coupling with protons, and the average J(Si-H) should be reduced by a factor of 1/6. We thank R. Simionescu for the explanation of this spectral feature.
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    • Combinatorial formula has been applied
    • Combinatorial formula has been applied.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.