Attempted reduction of 1,2,3-thiadiazole-4-carboxylates with samarium/iodine in methanol. Unexpected ring enlargement to 1,2,5-trithiepan-4, 6-dicarboxylates

Organic and Biomolecular Chemistry

Volumn 2, Issue 19, 2004, Pages 2870-2873

  Miyawaki, Kazuhiro ^a   Suzuki, Hitomi ^b   Morikawa, Hiromichi ^a,c  

^a JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

^b KWANSEI GAKUIN UNIVERSITY   (Japan)

^c HIROSHIMA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; CARBOXYLATION; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; IODINE; ISOMERS; METHANOL; MIXTURES; NITROGEN COMPOUNDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PURIFICATION; REDUCTION; SAMARIUM; STOICHIOMETRY;

1,2,3-THIADIAZOLES; CHEMICAL STABILITY; INTRACTABLE MIXTURES; RING ENLARGED PRODUCTS;

ORGANIC COMPOUNDS;

1,2,3 THIADIAZOLE 4 CARBOXYLIC ACID; 1,2,3-THIADIAZOLE-4-CARBOXYLIC ACID; IODINE; METHANOL; SAMARIUM; SINGLE HETEROCYCLIC RINGS; THIADIAZOLE DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; OXIDATION REDUCTION REACTION;

HETEROCYCLIC COMPOUNDS, 1-RING; IODINE; METHANOL; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; SAMARIUM; THIADIAZOLES;

EID: 6344267081     PISSN: 14770520     EISSN: None     Source Type: Journal    
DOI: 10.1039/b408195a     Document Type: Article

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