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33645928346
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note
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+)] generated in situ by replacement of the diethylamino group of 7 with /PrO. The exchange of an amino group was already reported in ref. 6.
-
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41
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0003942864
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Wiley, New York
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2v) similar to cis-1,2-dimethylcyclohexane, although the planar representation of 2 implies that it has a meso-configuration. Thus, 2 is a racemic mixture of two enantiomeric conformers which are interconvertible by a rapid ring flip. See: E. L. Eliel, S. H. Wilen and L. N. Mander, Stereochemistry of Organic Compounds, Wiley, New York, 1994, p. 703.
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33645910285
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The desymmetrization of 2b and the seven-membered disulfides, 3a and 3b, is assumed to be in the same sense by analogy
-
The desymmetrization of 2b and the seven-membered disulfides, 3a and 3b, is assumed to be in the same sense by analogy.
-
-
-
-
45
-
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33645942171
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-
a ≈ 0) by calculation based on the enantiomeric excess (36% ee)
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a ≈ 0) by calculation based on the enantiomeric excess (36% ee).
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0001456974
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