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It is well known that phosphates have a tendency to bind to metal oxide surfaces such as TiO2. To assess whether the OP compounds investigated in this study could bind to the TiO2 surface, we prepared known concentrations of either ethion, fenthion, or DCP. We immersed a TiO2 slide in each of the solutions, and after 24 hours removed the slide and measured the concentration of each of the OP compounds. In each case, there is loss in the concentration of the OP compound (assessed by UV-visible absorbance or GC-MS analysis of the solution after the TiO2 slide was removed), which suggests that some of the compound may be adsorbed to the TiO2 surface. On the other hand, comparable experiments conducted with FMN functionalized TiO2 showed no significant changes in the concentration of any of the OP pesticides.
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