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Volumn 131, Issue 2, 2009, Pages 440-441

Synthesis and spectroscopic identification of a μ-1,2-disulfidodinickel complex

Author keywords

[No Author keywords available]

Indexed keywords

CHARGE TRANSFER TRANSITIONS; DENSITY FUNCTIONAL THEORY CALCULATIONS; ELEMENTAL SULFUR; NICKEL PRECURSOR; RESONANCE RAMAN EXCITATION PROFILES; SPECTROSCOPIC IDENTIFICATION; SPECTROSCOPIC METHOD; VIBRATIONAL FEATURES;

EID: 62849103097     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja807735a     Document Type: Article
Times cited : (17)

References (18)
  • 1
    • 0000392369 scopus 로고    scopus 로고
    • Transition Metal Sulfur Chemistry: Biological and Industrial Significance
    • American Chemical Society: Washington, DC
    • Transition Metal Sulfur Chemistry: Biological and Industrial Significance; ACS Symposium Series 635; American Chemical Society: Washington, DC, 1996.
    • (1996) ACS Symposium Series , vol.635
  • 16
    • 67849126730 scopus 로고    scopus 로고
    • As shown in the Supporting Information, a fit of the VT 2H NMR spectral data to the effective Hamiltonian that leads to this coupling constant is not statistically better than a fit to a simple Curie paramagnet. However, given the S 0 ground state determined by MCD measurements and the lack of an EPR signal, we put forth an antiferromagnetically coupled dimer as the appropriate model for 2.
    • As shown in the Supporting Information, a fit of the VT 2H NMR spectral data to the effective Hamiltonian that leads to this coupling constant is not statistically better than a fit to a simple Curie paramagnet. However, given the S ) 0 ground state determined by MCD measurements and the lack of an EPR signal, we put forth an antiferromagnetically coupled dimer as the appropriate model for 2.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.