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Volumn 12, Issue 4, 2009, Pages 321-324

A novel 1-D coordination Cu(II) polymer with alternating μ1,3-squarato and binucleating polypyridylamine bridges

Author keywords

1D complexes; Copper complexes; Crystal structure; Magnetic properties; Squarato bridges

Indexed keywords


EID: 62649170576     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2009.02.006     Document Type: Article
Times cited : (17)

References (49)
  • 35
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    • and references therein
    • Robl C., and Weiss A. Z. Naturforsch. 41b (1986) 1490 and references therein
    • (1986) Z. Naturforsch. , vol.41 b , pp. 1490
    • Robl, C.1    Weiss, A.2
  • 38
    • 0003008954 scopus 로고
    • Valentine J.D., Foote C.S., Greenberg A., and Liebman J.F. (Eds), Blackie, Academic and Professional, Glasgow
    • Fox S., and Karlin K.D. In: Valentine J.D., Foote C.S., Greenberg A., and Liebman J.F. (Eds). Active Oxygen in Biochemistry (1995), Blackie, Academic and Professional, Glasgow 188
    • (1995) Active Oxygen in Biochemistry , pp. 188
    • Fox, S.1    Karlin, K.D.2
  • 39
    • 62649174659 scopus 로고    scopus 로고
    • note
    • 3CN: 456, 604 (br), 740 (sh). Caution: Salts of perchlorate and their metal complexes are potentially explosive and should be handled with great care and in small quantities.
  • 41
    • 62649148497 scopus 로고    scopus 로고
    • note
    • 2-).
  • 42
    • 62649144740 scopus 로고    scopus 로고
    • note
    • C = 39.4 ppm). Elemental analyses were carried out by the Atlantic Microlaboratory, Norcross, Georgia U.S.A. Cyclic voltammetry was carried out with a 3-electrode system comprised of a Pt counter electrode, a Pt disk working electrode, and a saturated calomel electrode (SCE) connected to the main cell compartment by a KCl salt bridge. Potential control was done with a BAS CV-50 W voltammetric analyzer used in the cyclic voltammetry mode. The supporting electrolyte was 0.1000 M NaCl (aq). Argon was bubbled through the solution for at least 30 min prior to insertion of the working electrode into solution. No bubbling was done while doing cyclic voltammetry. Susceptibility measurements were carried out with a Quantum-Design MPMS-5S SQUID magnetometer equipped with a 5 Tesla magnet in the range from 295 to 2.0 K. The powdered samples were contained in a gel bucket and fixed in a non-magnetic sample holder. Each raw data file for the measured magnetic moment was corrected for the diamagnetic contribution of the sample holder and the gel bucket. The molar susceptibility data were corrected using the Pascal constant and the increment method [34]. Crystal Data and structural analysis are given in the Supplementary mateial.
  • 46
    • 62649102424 scopus 로고    scopus 로고
    • note
    • Simulation of the experimental magnetic data with a full-matrix diagonalisation of exchange coupling and Zeeman splitting was performed with the julX program (E. Bill, Max-Planck Institute for Bioinorganic Chemistry, Mülheim/Ruhr, Germany).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.