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3CN: 456, 604 (br), 740 (sh). Caution: Salts of perchlorate and their metal complexes are potentially explosive and should be handled with great care and in small quantities.
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note
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2-).
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42
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62649144740
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note
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C = 39.4 ppm). Elemental analyses were carried out by the Atlantic Microlaboratory, Norcross, Georgia U.S.A. Cyclic voltammetry was carried out with a 3-electrode system comprised of a Pt counter electrode, a Pt disk working electrode, and a saturated calomel electrode (SCE) connected to the main cell compartment by a KCl salt bridge. Potential control was done with a BAS CV-50 W voltammetric analyzer used in the cyclic voltammetry mode. The supporting electrolyte was 0.1000 M NaCl (aq). Argon was bubbled through the solution for at least 30 min prior to insertion of the working electrode into solution. No bubbling was done while doing cyclic voltammetry. Susceptibility measurements were carried out with a Quantum-Design MPMS-5S SQUID magnetometer equipped with a 5 Tesla magnet in the range from 295 to 2.0 K. The powdered samples were contained in a gel bucket and fixed in a non-magnetic sample holder. Each raw data file for the measured magnetic moment was corrected for the diamagnetic contribution of the sample holder and the gel bucket. The molar susceptibility data were corrected using the Pascal constant and the increment method [34]. Crystal Data and structural analysis are given in the Supplementary mateial.
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62649102424
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note
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Simulation of the experimental magnetic data with a full-matrix diagonalisation of exchange coupling and Zeeman splitting was performed with the julX program (E. Bill, Max-Planck Institute for Bioinorganic Chemistry, Mülheim/Ruhr, Germany).
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