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Volumn 12, Issue 4, 2009, Pages 336-339

Syntheses, characterizations, and redox behaviors of new self-assembled metal complexes with bridging ligands incorporating chalcogen sites

Author keywords

Chalcogen site; Coordination polymer; Crystal structure; Redox property

Indexed keywords


EID: 62649104126     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2009.02.014     Document Type: Article
Times cited : (8)

References (26)
  • 20
    • 62649086229 scopus 로고    scopus 로고
    • note
    • 2sdp (125 mg, 0.5 mmol), and phen (90 mg, 0.5 mmol) was refluxed for 3 h. The solution was filtered out and was stood for a few days. The crystals obtained were collected by filtration.
  • 21
    • 62649134871 scopus 로고    scopus 로고
    • note
    • -1, reflections collected 16,729, unique reflections 7217, param refined 613, R = 0.0840, wR = 0.1239, GOF = 1.302.
  • 25
    • 62649088584 scopus 로고    scopus 로고
    • note
    • The solid-state cyclic voltammogram (CV) measurements were carried out by immobilization of the sample at the working electrode surface according to the literature [26]. The glassy carbon electrode was gently rubbed over the crystalline sample (1-3 mg) for each compound in order to immobilize their compounds at the electrode surface. SCE and platinum wire were used as reference and counter electrodes, respectively as similar to the solution-state measurements. The three electrodes were immersed in an acetonitrile solution containing tetra-n-buylammonium hexafluorophosphate (100 mM) as an electrite. The acetonitrile solution was degassed with nitrogen for a few minutes prior to the measurements. After each measurement, the working electrode surface was cleaned with a razor blade.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.