Electron-deficient iron alkyl complexes supported by diimine ligand (Ph2CN)2C2H4: Evidence for reversible ethylene binding

Organometallics

Volumn 28, Issue 1, 2009, Pages 209-215

  Volbeda, Jeroen ^a   Meetsma, Auke ^a   Bouwkamp, Marco W ^a  

^a UNIVERSITY OF GRONINGEN   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYLATION; CHLORINE COMPOUNDS; DYES; ETHYLENE; FULLERENES; IRON; LIGANDS; POLYMERS; RARE EARTH COMPOUNDS; TOLUENE;

ALKYL COMPLEXES; BROMOBENZENE; CONTACT ION PAIRS; DICATION; DIIMINE LIGANDS; ELECTRON DEFICIENTS; ELEVATED TEMPERATURES; ETHYLENE BINDINGS; FERROUS CHLORIDES; FERROUS COMPLEXES; METHYL ALUMINOXANE; ROOM TEMPERATURES; TOLUENE SOLUTIONS;

IRON COMPOUNDS;

EID: 61849102822     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om8006773     Document Type: Article

References (44)

1. Small, B. L.; Brookhart, M; Bennett, A. M. A. J. Am. Chem. Soc. 1998, 120, 4049.
2. Britovsek, G. J. P.; Gibson, V. C; Kimberely, B. S.; Maddox, P. J.; McTavish, S. J.; Solan, G. A.; White, A. J. P.; Williams, D. J. Chem. Commun. 1998, 849.
3. For recent reviews on iron-catalyzed olefin polymerization catalysis, see: Bianchini, C; Giambastiania, G.; Guerrero Rios, I.; Mantovani, G.; Meli, A.; Segarra, A. M. Coord. Chem. Rev. 2006, 250, 1391.
4. Gibson, V. C; Redshaw, C; Solan, G. A. Chem. Rev. 2007, 107, 1745.
5. (a) Deng, L.; Margl, P.; Ziegler, T. J. Am. Chem. Soc. 1999, 121, 6479.
6. (b) Babik, S. T.; Fink, G. J. Mol. Catal. A 2002, 188, 245.
7. (c)Britovsek, G. J. P.; Gibson, V. C; Spitzmesser, S. K.; Tellman, K. P.; White, A. J. P.; Williams, D. J. J. Chem. Soc, Dalton Trans. 2002, 1159.
8. (d)Bryliakov, K. P.; Semikolenova, N. V.; Zudin, V. N.; Zakharov, V. A.; Talsi, E. P. Catal. Commun. 2004, 5, 45.
9. (e) Castro, P. M.; Lahtinen, P.; Axenov, K.; Viidanoja, J.; Kotiaho, T.; Leskelä, M; Repo, T. Organometallics 2005, 24, 3664.
10. Scott, J.; Gambarotta, S.; Korobkov, I.; Budzelaar, P. H. M. Organometallics 2005, 24, 6298.
11. (a) Britovsek, G. J. P.; Clentsmith, G. K. B.; Gibson, V. C; Goodgame, D. M. L.; McTavish, S. J.; Pankhurst, Q. A. Catal. Commun. 2002, 3, 207.
12. (b) Raucoules, R.; De Bruin, T.; Raybaud, P.; Adamo, C. Organometallics 2008, 27, 3368-3377.
13. (a) Bouwkamp, M. W.; Bart, S. C; Hawrelak, E. J.; Trovitch, R. J.; Lobkovsky, E.; Chirik, P. J. Chem. Commun. 2005, 3406.
14. (b) Scott, J.; Gambarotta, S.; Korobkov, I.; Budzelaar, P. H. M. J. Am. Chem. Soc. 2005, 127, 13019.
15. (c) Cámpora, J.; Naz, A. M.; Palma, P.; Alvarez, E.; Reyes, M. L. Organometallics 2005, 24, 4878.
16. Bouwkamp, M. W.; Lobkovsky, E.; Chirik, P. J. J. Am. Chem. Soc. 2005, 127, 9660.
17. Scott, J.; Gambarotta, S.; Korobkov, I.; Knijnenburg, Q.; De Bruin, B.; Budzelaar, P. H. M. J. Am. Chem. Soc. 2005, 127, 17204.
18. (a) Tripathi, S. C; Srivastava, S. C; Shrimal, A. K.; Singh, O. P. Inorg. Chim. Acta 1985, 98, 19.
19. (b) Paz-Sandoval, M. A.; Domínguez-Durán, M. E.; Pazos-Mayen, C; Ariza-Castolo, A.; Rosales-Hoz, M. J.; Contretas, R. J. Organomet. Chem. 1995, 492, 1.
20. (c) Petrovski, Z.; Pillinger, M.; Valente, A. A.; GonçLalves, I. S.; Hazell, A.; Romão, C. C. J. Mol. Catal. A: Chem. 2005, 227, 67.
21. (d) Kia, R.; Mirkhani, V.; Kalman, A.; Deak, A. Polyhedron 2007, 26, 1711.
22. Bart, S. C; Hawrelak, E. J.; Schmisseur, A. K.; Lobkovsky, E.; Chirik, P. J. Organometallics 2004, 23, 237.
23. 5. These crystals were used for a single-crystal X-ray analysis.
24. Kervern, G.; Pintacuda, G.; Zhang, Y.; Oldfield, E.; Roukoss, C; Kuntz, E.; Herdtweck, E.; Basset, J. M.; Cadars, S.; Lesage, A.; Copéret, C; Emsley, L. J. Am. Chem. Soc. 2006, 128, 13545.
25. (a) Scott, J.; Gambarotta, S.; Korobkov, I.; Budzelaar, P. H. M. Organometallics 2005, 24, 6298.
26. (b) Fernandez, I.; Trovitch, R. J.; Lobkovsky, E.; Chirik, P. J. Organometallics 2008, 27, 109.
27. (a) Sciarone, T. J. J.; Meetsma, A.; Hessen, B.; Teuben, J. H. Chem. Commun. 2002, 1580.
28. (b) Sciarone, T. J. J.; Meetsma, A.; Hessen, B. Inorg. Chim. Acta 2006, 359, 1815.
29. (c) Sciarone, T. J. J.; Nijhuis, C. A.; Meetsma, A.; Hessen, B. Organometallics 2008, 27, 2058.
30. Lee, H.; Hong, S.-D.; Park, Y.-W.; Jeong, B.-G.; Nam, D.-W.; Jung, H. Y.; Jung, M. W.; Song, K. H. J. Organomet. Chem. 2004, 689, 3402.
31. (a) Beck, S.; Lieber, S.; Schaper, F.; Geyer, A.; Brintzinger, H.-H. J. Am. Chem. Soc. 2001, 123, 1483.
32. (b) Stahl, N. G.; Zuccaccia, C; Jensen, T. R.; Marks, T. J. J. Am. Chem. Soc. 2003, 125, 5256.
33. (c) Zuccaccia, C; Stahl, N. G.; Macchioni, A.; Chen, M.-C; Roberts, J. A.; Marks, T. J. J. Am. Chem. Soc. 2004, 126, 1448.
34. Horton, A. D.; De With, J.; Van der Linden, A. J.; Van de Weg, H. Organometallics 1996, 15, 2672.
35. Single crystals were also obtained from a thermolysis experiment (50 °C) of 5a in toluene. This afforded a similar structure, but with cyclohexane rather than bromobenzene cocrystallized in the lattice. The cif file of the crystals structure determination can be found in the Supporting Information.
36. Sciarone, T. J. J.; Nijhuis, C. A.; Meetsma, A.; Hessen, B. Dalton Trans. 2006, 4896.
37. Kovacic, P.; Brace, N. O. Inorg. Synth, 1960, 6, 172.
38. Ariza-Castolo, A.; Paz-Sandoval, M. A.; Contreras, R. Magn. Reson. Chem. 1992, 30, 520.
39. Lewis, H. L.; Brown, T. L. J. Am. Chem. Soc. 1970, 92, 4664.
40. Eshuis, J. J. W.; Tan, Y. Y.; Meetsma, A.; Teuben, J. H.; Renkema, J.; Evens, G. G. Organometallics 1992, 11, 362.
41. Pohlmann, J. L. W.; Brinckmann, F. E. Z. Naturforsch. B 1965, 20, 5.
42. Sur, S. K. J. Magn. Reson. 1989, 82, 169.
43. Sheldrick, G. M. SADABS v2, Multi-Scan Absorption Correction Program; University of Göttingen: Germany, 2001.
44. Beurskens, P. T.; Beurskens, G.; De Gelder, R.; García-Granda, S.; Gould, R. O.; Israël, R.; Smits, J. M. M. The DIRDIF-99 Program System; Crystallography Laboratory, University of Nijmegen: The Netherlands, 1999.