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Volumn 28, Issue 1, 2009, Pages 270-276

The first phenanthrene-fused imidazol-2-ylidene and its transition-metal complexes

Author keywords

[No Author keywords available]

Indexed keywords

AG COMPLEXES; AIR STABLES; FLUORESCENCE EMISSION SPECTRUM; IMIDAZOL; IMIDAZOLIUM SALTS; N-HETEROCYCLIC CARBENE; SILVER COMPLEXES; SOLID-STATE MOLECULAR STRUCTURES; TRANSITION-METAL COMPLEXES; X-RAY DIFFRACTION STUDIES;

EID: 61849093631     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om800822m     Document Type: Article
Times cited : (54)

References (39)
  • 12
    • 61849171008 scopus 로고    scopus 로고
    • Ph.D.Thesis, University of Alabama, Tuscaloosa
    • (h) Li, W. Ph.D.Thesis, University of Alabama, Tuscaloosa, 2004.
    • (2004)
    • Li, W.1
  • 15
    • 0000181676 scopus 로고    scopus 로고
    • A similar carbene precursor, 1,3-dimethylphenanthro[9,10-c]imida-zolium iodide, has been reported (without characterization) as a catalyst for benzoin condensation: Miyashita, A.; Suzuki, Y.; Kobayashi, M.; Kuriyama, N.; Higashino, T. Heterocycles 1996, 43, 509.
    • A similar carbene precursor, 1,3-dimethylphenanthro[9,10-c]imida-zolium iodide, has been reported (without characterization) as a catalyst for benzoin condensation: Miyashita, A.; Suzuki, Y.; Kobayashi, M.; Kuriyama, N.; Higashino, T. Heterocycles 1996, 43, 509.
  • 20
    • 61849110193 scopus 로고    scopus 로고
    • To avoid concentration, we attempted to crystallize carbene 5 by slow diffusion of hexane into a saturated THF solution of 5. No crystals were obtained. After 6 days the obtained brown solution was treated with sulfur. The resulting thione was recovered in 76% yield. Further details on the synthesis of this thione and its coordination properties will be reported elsewhere.
    • To avoid concentration, we attempted to crystallize carbene 5 by slow diffusion of hexane into a saturated THF solution of 5. No crystals were obtained. After 6 days the obtained brown solution was treated with sulfur. The resulting thione was recovered in 76% yield. Further details on the synthesis of this thione and its coordination properties will be reported elsewhere.
  • 36
    • 28444463655 scopus 로고    scopus 로고
    • For a review on silver complexes see
    • For a review on silver complexes see: Garrison, J. C.; Youngs, W. J. Chem. Rev. 2005, 105, 3978.
    • (2005) Chem. Rev , vol.105 , pp. 3978
    • Garrison, J.C.1    Youngs, W.J.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.