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The structure of 2b was not taken into consideration for this calculation.
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The structure of 2b was not taken into consideration for this calculation.
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61749102379
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The intemuclear distances Ni-N and Ni-O are 1.889(22) and 1.882(21) Å in the molecular structure of Ni(salen) obtained from gas-phase electron diffraction.
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The intemuclear distances Ni-N and Ni-O are 1.889(22) and 1.882(21) Å in the molecular structure of Ni(salen) obtained from gas-phase electron diffraction.
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The fact that a polymorph of Co(salen, refcode: VEXLIU) is isomorphous with Ni(salen) is surprising. The very small difference in Co-Co and Ni-Ni distances (less than 0.03 Å) is also a surprise because d 8-d8 interactions are expected to be stronger than d 7-d7 interactions, see ref 42. The structure of a different polymorph of Co(salen) has been also described when Co is found in a five coordination environment (refcodes: ESAICO and ESAICO01, which is very different from that found in VEXLIU, see: (a) Bruckner, S, Calligaris, M, Nardin, G, Randaccio, L. Acta Crystallogr. 1969, B25, 1671-1674
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7 interactions, see ref 42. The structure of a different polymorph of Co(salen) has been also described when Co is found in a five coordination environment (refcodes: ESAICO and ESAICO01), which is very different from that found in VEXLIU, see: (a) Bruckner, S.; Calligaris, M.; Nardin, G.; Randaccio, L. Acta Crystallogr. 1969, B25, 1671-1674.
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The use of the term co-crystal has been extensively debated in the literature and there seems to be not yet any agreement about the matter. In this study, the term co-crystal is referred to as a multi-component molecular crystal, in which two or more components are neutral molecules and solid at room temperature. If one component is a liquid at room temperature, the term solvate is used, see ref 30
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The use of the term "co-crystal" has been extensively debated in the literature and there seems to be not yet any agreement about the matter. In this study, the term "co-crystal" is referred to as a multi-component molecular crystal, in which two or more components are neutral molecules and solid at room temperature. If one component is a liquid at room temperature, the term "solvate" is used, see ref 30.
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