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Volumn 9, Issue 2, 2009, Pages 1194-1200

Ni(salen): A system that forms many solvates with interacting Ni atoms

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Indexed keywords


EID: 61749100279     PISSN: 15287483     EISSN: 15287505     Source Type: Journal    
DOI: 10.1021/cg801109n     Document Type: Article
Times cited : (53)

References (45)
  • 8
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    • in preparation
    • Lutz, M. 2008, in preparation.
    • (2008)
    • Lutz, M.1
  • 11
    • 20444463038 scopus 로고    scopus 로고
    • WinXmorph, Version 1.0, Release 4, Build 6; Department of Chemistry, University of Washington: Seattle, WA. Kaminsky, W. J. Appl. Crystallogr. 2005, 38, 566-567
    • WinXmorph, Version 1.0, Release 4, Build 6; Department of Chemistry, University of Washington: Seattle, WA. Kaminsky, W. J. Appl. Crystallogr. 2005, 38, 566-567.
  • 12
    • 0004182772 scopus 로고    scopus 로고
    • Nonius BV: Delft, The Netherlands
    • Nonius. COLLECT; Nonius BV: Delft, The Netherlands, 1999.
    • (1999) COLLECT
    • Nonius1
  • 13
    • 30744475930 scopus 로고    scopus 로고
    • University of Utrecht: The Netherlands
    • Schreurs, A. M. M. PEAKREF; University of Utrecht: The Netherlands, 2005.
    • (2005) PEAKREF
    • Schreurs, A.M.M.1
  • 21
    • 61749097568 scopus 로고    scopus 로고
    • The structure of 2b was not taken into consideration for this calculation.
    • The structure of 2b was not taken into consideration for this calculation.
  • 24
    • 61749102379 scopus 로고    scopus 로고
    • The intemuclear distances Ni-N and Ni-O are 1.889(22) and 1.882(21) Å in the molecular structure of Ni(salen) obtained from gas-phase electron diffraction.
    • The intemuclear distances Ni-N and Ni-O are 1.889(22) and 1.882(21) Å in the molecular structure of Ni(salen) obtained from gas-phase electron diffraction.
  • 26
    • 61749103137 scopus 로고    scopus 로고
    • The fact that a polymorph of Co(salen, refcode: VEXLIU) is isomorphous with Ni(salen) is surprising. The very small difference in Co-Co and Ni-Ni distances (less than 0.03 Å) is also a surprise because d 8-d8 interactions are expected to be stronger than d 7-d7 interactions, see ref 42. The structure of a different polymorph of Co(salen) has been also described when Co is found in a five coordination environment (refcodes: ESAICO and ESAICO01, which is very different from that found in VEXLIU, see: (a) Bruckner, S, Calligaris, M, Nardin, G, Randaccio, L. Acta Crystallogr. 1969, B25, 1671-1674
    • 7 interactions, see ref 42. The structure of a different polymorph of Co(salen) has been also described when Co is found in a five coordination environment (refcodes: ESAICO and ESAICO01), which is very different from that found in VEXLIU, see: (a) Bruckner, S.; Calligaris, M.; Nardin, G.; Randaccio, L. Acta Crystallogr. 1969, B25, 1671-1674.
  • 35
    • 61749092131 scopus 로고    scopus 로고
    • The use of the term co-crystal has been extensively debated in the literature and there seems to be not yet any agreement about the matter. In this study, the term co-crystal is referred to as a multi-component molecular crystal, in which two or more components are neutral molecules and solid at room temperature. If one component is a liquid at room temperature, the term solvate is used, see ref 30
    • The use of the term "co-crystal" has been extensively debated in the literature and there seems to be not yet any agreement about the matter. In this study, the term "co-crystal" is referred to as a multi-component molecular crystal, in which two or more components are neutral molecules and solid at room temperature. If one component is a liquid at room temperature, the term "solvate" is used, see ref 30.
  • 44
    • 61749102090 scopus 로고    scopus 로고
    • Hursthouse, M. B. (2003) Private Communication to the Cambridge Structural Database, deposition number CCDC 216016.
    • Hursthouse, M. B. (2003) Private Communication to the Cambridge Structural Database, deposition number CCDC 216016.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.