Kinetics of solvent-free geranyl acetate synthesis by Rhizopus oligosporus NRRL 5905 lipase immobilized on to cross-linked silica

Biocatalysis and Biotransformation

Volumn 27, Issue 2, 2009, Pages 124-130

  Mahapatra, Paramita ^a   Kumari, Annapurna ^a   Kumar, Garalapati V ^a   Banerjee, Rintu ^a   Nag, Ahindra ^a  

^a INDIAN INSTITUTE OF TECHNOLOGY   (India)

Author keywords

Geranyl acetate; Kinetics; Silica immobilized lipase; Solvent free; Transesterification

Indexed keywords

ACYL DONORS; ENZYME CONCENTRATIONS; FIRST-ORDER KINETIC MODELS; GERANYL ACETATE; MICHAELIS-MENTEN KINETICS; MOLAR CONVERSIONS; PHYSICAL PARAMETERS; PSEUDO FIRST ORDERS; REACTION MIXTURES; REACTION TEMPERATURES; REACTION TIME; RHIZOPUS OLIGOSPORUS; SHAKING SPEED; SOLVENT FREE; SOLVENT-FREE SYNTHESIS; SUBSTRATE CONVERSIONS; VINYL ACETATES; WATER AMOUNTS;

ENZYME ACTIVITY; ENZYMES; ESTERIFICATION; GELATION; ORGANIC SOLVENTS; REACTION RATES; SILICA; SILICA GEL; TRANSESTERIFICATION;

OXIDES;

EID: 61649128252     PISSN: 10242422     EISSN: 10292446     Source Type: Journal    
DOI: 10.1080/10242420802583366     Document Type: Article

References (22)

1. Akoh, CC and Yee, LN (1998) Lipase-catalysed transesterification of primary terpene alcohols with vinyl esters in organic media. J Mol Catal B: Enzym, 4, pp. 149-153.
2. Chulalaksananukul, W., Condoret, JS and Combes, D. (1992) Kinetics of geranyl acetate synthesis by lipase-catalysed transesterification in n-hexane. Enzyme Microb Technol, 14, pp. 293-298.
3. Claon, PA and Akoh, CC (1993) Enzymatic synthesis of geraniol and citronellol esters by direct esterification in n-hexane. Biotechnol Lett, 15, pp. 1211-1216.
4. Claon, PA and Akoh, CC (1994) Enzymatic synthesis of geranyl acetate in n-hexane with Candida antarctica lipases. J Am Oil Chemists Soc, 71, pp. 575-578.
5. Croteau, R. (1980) The biosynthesis of terpene compound. Fragrance and flavor substances, pp. 13-14. D & PS Verlag, Germany
6. Foresti, ML and Ferreira, ML (2007) Chitosan-immobilized lipases for the catalysis of fatty acid esterifications. Enzyme Microb Technol, 40, pp. 769-777.
7. Garcia, T., Sanchez, N., Martinez, M. and Aracil, J. (1999) Enzymatic synthesis of fatty esters. Part I. Kinetic approach. Enzyme Microb Technol, 25, pp. 584-590.
8. Ghamgui, H., Karra-chaabouni, M. and Gargouri, Y. (2004) 1-Butyl oleate synthesis by immobilized lipase from Rhizopus oryzae: A comparative study between n-hexane and solvent-free system. Enzyme Microb Technol, 35, pp. 355-363.
9. 2 gel fiber. J Am Oil Chemists Soc, 78, pp. 1099-1103.
10. Kim, M., Il, Ham, HO, Oh, S-D, Park, HG, Chang, HN and Choi, S-H. (2006) Immobilization of Mucor javanicus lipase on effectively functionalized silica nanoparticles. J Mol Catal B: Enzym, 39, pp. 62-68.
11. Klibanov, AM (1997) Why are enzymes less active in organic solvents than in water?. Trends Biotechnol, 15, pp. 97-101.
12. Kordel, M., Hofmann, B., Schomburg, D. and Schmid, RD (1991) Extracellular lipase of Pseudomonas sp. strain ATCC-21808, purification, characterization, crystallization, and preliminary X-ray diffraction data. J Bacteriol, 173, pp. 4836-4841.
13. Krings, U. and Berger, RG (1998) Biotechnological production of flavours and fragrances. Appl Microbiol Biotechnol, 49, pp. 1-8.
14. Malcata, FX, Reyes, HR, Garcia, HS, Hill, CG and Amundson, CH (1992) Kinetics and mechanisms of reactions catalysed by immobilized lipases. Enzyme Microb Technol, 14, pp. 426-446.
15. Molinari, F., Villa, R. and Aragozzini, F. (1998) Production of geranyl acetate and other acetates by direct esterification catalyzed by mycelium of Rhizopus delemar in organic solvent. Biotechnol Lett, 20, pp. 41-44.
16. Paez, BC, Medina, AR, Rubio, FC, Cerdan, LE and Grima, EM (2003) Kinetics of lipase-catalysed interesterification of triolein and caprylic acid to produce structured lipids. J Chem Technol Biotechnol, 78, pp. 461-470.
17. Paiva, AL, Victor, M., Balcao, F. and Malcata, X. (2000) Kinetics and mechanisms of reactions catalyzed by immobilized lipases. Enzyme Microb Technol, 27, pp. 187-204.
18. Rao, MN, Kembhavi, AA and Pant, A. (2000) Immobilization of endo-polygalacturonase from Aspergillus ustus on silica gel. Biotechnol Lett, 22, pp. 1557-1559.
19. Romero, MD, Calvo, L., Alba, C. and Daneshfar, A. (2005) Enzymatic synthesis of isoamyl acetate with immobilized Candida antarctica lipase in n-hexane. Enzyme Microb Technol, 37, pp. 42-48.
20. Sheldon, RA (1996) Large-scale enzymatic conversions in non-aqueous media. Enzymatic reactions in organic media, pp. 266-307. Blackie Academic and Professional, Glasgow
21. Teo, HTR and Saha, B. (2004) Heterogeneous catalysed esterification of acetic acid with isoamyl alcohol: Kinetic studies. J Catal, 228, pp. 174-182.
22. Trusek-Holownia, A. and Noworyta, A. (2007) An integrated process: Ester synthesis in an enzymatic membrane reactor and water sorption. J Biotechnol, 130, pp. 47-56.