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The core NRs were synthesized using a multiple injection method and subsequently capped with an intermediate ZnSe shell and an outer ZnS shell. The experimental details are provided in the Supporting Information. The fluorescence quantum yield, estimated with respect to Rhodamine 6G, increased from 0.3, core to a maximum of 10, core/shell
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The core NRs were synthesized using a multiple injection method and subsequently capped with an intermediate ZnSe shell and an outer ZnS shell. The experimental details are provided in the Supporting Information. The fluorescence quantum yield, estimated with respect to Rhodamine 6G, increased from 0.3% (core) to a maximum of 10% (core/shell).
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14
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84868903914
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on < 1 s) according to the procedure described in ref 12, which gives good fits and consistent fitting parameters for different emitters.
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on < 1 s) according to the procedure described in ref 12, which gives good fits and consistent fitting parameters for different emitters.
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16
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0001618724
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For a power-law fit to the data on a linear scale see for example ref 3 and the discussion therein. For a linear fit see for example
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For a linear fit see for example: Kuno, M.; Fromm, D. P.; Hamann, H. F.; Gallagher, A.; Nesbitt, D. J. J. Chem. Phys. 2000, 112, 3117-3120, For a power-law fit to the data on a linear scale see for example ref 3 and the discussion therein.
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18
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84868903915
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16 As an example, rotating the laser polarization by 90° in the case of the two NRs, shown in Figure 4b, decreased their maximum emission intensity to ∼10% of the initial integrated intensity as θ increased from ∼15° to ∼75°, which is in good agreement with the expected angle dependence. Details for this and a few other examples are given in the Supporting Information.
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16 As an example, rotating the laser polarization by 90° in the case of the two NRs, shown in Figure 4b, decreased their maximum emission intensity to ∼10% of the initial integrated intensity as θ increased from ∼15° to ∼75°, which is in good agreement with the expected angle dependence. Details for this and a few other examples are given in the Supporting Information.
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84868903490
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The obtained values of αoff and α n are close to those previously reported for NR blinking on mica (cf. ref 3, However, the characteristic time τon c associated with the exponential decay is shorter for Si 3N4 (τonc, 1.3 s) compared to mica τonc, 4.0 s
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c = 4.0 s).
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23
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84868903494
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th time interval of 0.1 s.
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th time interval of 0.1 s.
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