Catalytic supercritical water oxidation for the destruction of quinoline over MnO2/CuO mixed catalyst

Industrial and Engineering Chemistry Research

Volumn 48, Issue 3, 2009, Pages 1208-1214

  Angeles Hernández, Mauricio J ^a   Leeke, Gary A ^a   Santos, Regina C D ^a  

^a UNIVERSITY OF BIRMINGHAM   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CATALYSTS; COPPER OXIDES; EQUATIONS OF STATE; KINETIC THEORY; MANGANESE COMPOUNDS; ORGANIC COMPOUNDS; OXYGEN; PRESSURE EFFECTS; REACTION RATES; THERMAL EFFECTS;

CATALYTIC REACTIONS; CRITICAL POINTS; EXPERIMENTAL DATUM; FIXED-BED REACTORS; HETEROCYCLIC ORGANIC COMPOUNDS; KINETIC DATUM; KINETIC MODELS; LANGMUIR-HINSHELWOOD-HOUGEN-WATSON; OPERATING CONDITIONS; OXYGEN CONCENTRATIONS; POWER LAWS; SUPERCRITICAL CONDITIONS; SUPERCRITICAL WATER OXIDATIONS;

CATALYTIC OXIDATION;

EID: 61549131170     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie8006402     Document Type: Article

References (34)

1. Webley, P. A.; Tester, J. W.; Holgate, H. R. Oxidation kinetics of ammonia and ammonia-methanol mixtures in supercritical water in the temperature range 530-700°C at 246 bar. Ind. Eng. Chem. Res. 1991, 30, 1745.
2. Savage, P. E.; Dunn, J. B.; Yu, J. Recent advances in catalytic oxidation in supercritical water. Combust. Sci. Technol. 2006, 178, 443.
3. Bermejo, M. D.; Cocero, M. J. Supercritical water oxidation: A technical review. AIChE J. 2006, 52, 3933.
4. Pinto, L. S. D. Supercritical water oxidation of nitrogen-containing organic compounds: Process operating conditions and reaction kinetics. Ph.D. Thesis. University of Birmingham, Birmingham, U.K., 2004.
5. Pinto, L. D. S.; Freitas dos Santos, L. M.; Al-Duri, B.; Santos, R. C. D. Supercritical water oxidation of quinoline in a continuous plug flow reactor - Part 1: Effect of key operating parameters. J. Chem. Technol. Biotechnol. 2006, 81, 912.
6. Nicolaescu, A. R.; Wiest, O.; Kamat, P. V. Mechanistic pathways of the hydroxyl radical reactions of quinoline. 1. Identification, distribution, and yields of hydroxylated products. J. Phys. Chem. A 2005, 109, 2822.
7. Segond, N.; Matsumura, Y.; Yamamoto, K. Determination of ammonia oxidation rate in sub- and supercritical water. Ind. Eng. Chem. Res. 2002, 41, 6020.
8. Zhang, X.; Savage, P. E. Fast catalytic oxidation of phenol in supercritical water. Catal. Today 1998, 40, 333.
9. Perego, C.; Peratello, S. Experimental methods in catalytic kinetics. Catal. Today 1999, 52, 133.
10. Angeles, M. J.; Al-Marzouqui, A. H.; Al-Duri, B.; Santos, R. C. D. Catalytic supercritical water oxidation for the destruction of DBU. I Iberoamerican Conference on Supercritical Fluids, ProSCiba, April 10-13th, Iguassu Falls, Brazil, 2007.
11. Aki, S. N. V. K.; Abraham, M. A. Catalytic supercritical water oxidation of pyridine: kinetics and mass transfer. Chem. Eng. Sci. 1999, 54, 3533.
12. Eckert, C. A.; Chandler, K. Tuning fluid solvents for chemical reactions. J. Supercrit. Fluids 1998, 13, 187.
13. Krajnc. M.; Levec, J. The role of catalyst in supercritical water oxidation of acetic acid. Appl. Catal., B 1997, 13, 93.
14. Dautzenberg, F. M. Ten guidelines for catalyst testing In Characterization and Catalyst Development; Bradley, S. A., Galhuso, M. J., Bertolacini, R. J., Eds.; ACS Symposium Series: Los Angeles, CA, 1989; Vol. 411, p 99.
15. Oshima, Y.; Tomita, K.; Koda, S. Kinetics of the catalytic oxidation of phenol over manganese oxide in supercritical water. Ind. Eng. Chem. Res. 1999, 38, 4183.
16. Froment, G. F.; Hosten, L. H. Catalytic Kinetics: Modelling. In Catalysis: Science and Technology; Anderson, J. R., Boudait, M., Eds.; Springer-Verlag: Berlin, 1990.
17. Press, W. H.; Teukolsky, S. A.; Vetterling, W. T.; Flannery, B. P. Numerical Recipes; Cambridge University Press: Cambridge, U.K., 2007.
18. Langtangen, H. P. Python Scripting for Computational Science; Springer-Verlag: Berlin, 2008.
19. Jones, E.; Oliphant, T.; Peterson, P.; Millman, J.; Kern, R.; van der Walt, S.; Hunter, J. D.; Perez, F.; Certik, O.; Kitterman, S. et al. SciPy: Open Source Scientific Tools for Python, http://www.scipy.org, 2001.
20. Pinto, L. D. S.; Freitas dos Santos, L. M.; Santos, R. C. D.; Al-Duri, B. Supercritical water oxidation of quinoline in a continuous plug flow reactor - Part 2: Kinetics. J. Chem. Technol. Biotechnol 2006, 81, 919.
21. Hill, C. G. An Introduction to Chemical Engineering and Reactor Design; Wiley: New York, 1977.
22. 2. Environ. Sci. Technol. 2000, 34, 3191.
23. 3 in supercritical water. Appl. Catal., B 2000, 28, 275.
24. Savage, P. E. Heterogeneous catalysis in supercritical water. Catal. Today 2000, 62, 167.
25. Krajnc, M.; Levee, J. Oxidation of phenol over transition-metal oxide catalyst in supercritical water. Ind Eng. Chem. Res. 1997, 36, 3439.
26. 2 in supercritical water. Ind Eng. Chem. Res. 1999, 38, 3793.
27. Aki, S.; Abraham, M. A. Catalytic supercritical water oxidation of pyridine: Comparison of catalysts. Ind. Eng. Chem. Res. 1999, 38, 358.
28. DiNaro, J. L.; Howard, J. B.; Green, W. H.; Tester, J. W.; Bozzelli, J. W. Elementary reaction mechanism for benzene oxidation in supercritical water. J. Phys. Chem. A 2000, 104, 10576.
29. Holgate, H. R.; Tester, J. W. Oxidation of hydrogen and carbon monoxide in sub- and supercritical water: Reaction kinetics, pathways and water-density effects. 2. Elementary reaction modeling. J. Phys. Chem, 1994, 98, 810.
30. Bühler, W.; Dinjus, E.; Ederer, H. J.; Kruse, A.; Mas, C. Ionic reactions and pyrolisis of glycerol as competing reaction pathways in near-and supercritical water. J. Supercrit. Fluids 2002, 22, 37.
31. Kruse, A.; Dinjus, E. Hot compressed water as a medium and reactant. 2. Degradation Reactions. J. Supercrit. Fluids 2007, 41, 361.
32. Levenspiel, O. Chemical reaction engineering. Ind. Eng. Chem. Res. 1999, 38, 4140.
33. Tomita, K.; Oshima, Y. Stability of manganese oxide in catalytic supercritical water oxidation of phenol. Ind. Eng. Chem. Res. 2004, 43, 7740.
34. Yu, J.; Savage, P. E. Catalyst activity, stability, and transformations during oxidation in supercritical water. Appl. Catal., B 2001, 31, 123.