Ionic reactions and pyrolysis of glycerol as competing reaction pathways in near- and supercritical water

Journal of Supercritical Fluids

Volumn 22, Issue 1, 2002, Pages 37-53

  Buhler W ^a   Dinjus, E ^a   Ederer, H J ^a   Kruse, A ^a   Mas, C ^a  

^a KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

Author keywords

Elementary reaction; High pressure; Ionic reaction; Supercritical water; Thermal decomposition

Indexed keywords

ACETALDEHYDE; ACROLEIN; ALCOHOL; ALLYL ALCOHOL; CARBON DIOXIDE; CARBON MONOXIDE; FORMALDEHYDE; FREE RADICAL; GLYCEROL; HYDROGEN; METHANOL; PROPIONALDEHYDE; WATER;

ARTICLE; CALCULATION; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; COMPUTER PROGRAM; DECOMPOSITION; HEATING; IONIZATION; MODEL; PRESSURE; PYROLYSIS; REACTION ANALYSIS;

EID: 0036137930     PISSN: 08968446     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0896-8446(01)00105-X     Document Type: Article

References (38)

1. Supercritical water oxidation: State of the Arte
2. Hydrolysis and oxidation in subcritical and supercritical water: Connecting process engineering science to molecular interaction
3. Supercritical water oxidation research and development update
4. Hydrothermal gasification of biomass and organic wastes
5. Modelling of the pyrolysis of tert-butylbenzene in supercritical water
6. Polyethylene conversion in supercritical water
7. Organic chemical reactions in supercritical water
8. Applications of high-temperature aqueous media for synthetic organic reactions
9. Supercritical water
10. The effect of salts on hydrolysis in supercritical and near-critical water: Reactivity and availability
11. Influence of water on guiacol pyrolysis
12. Reactions of diphenylether in supercritical water - Mechanism and kinetics
13. Reactions of di-n-butylphthalate in water at near-critical temperature and pressure
14. Acid/base catalysed esters hydrolysis in near-critical water
15. Effect of pressure on the rate of butylnitril hydrolysis in high-temperature water
16. Mechanism and temperature-dependent kinetics of the dehydration of tertbutyl alcohol in hot compressed liquid water
17. Noncatalytic organic synthesis using supercritical water: The peculiarity near the critical point
18. Pyrolytic sources of hydrocarbons from biomass
19. Acid-catalysed dehydration of alcohols in supercritical water
20. Hydrolysis in supercritical water: Solvent effects as a probe of the reaction mechanism
21. Hydrolysis of esters in subcritical and supercritical water
22. Nitrile hydrolysis kinetics: Pressure effects near the critical point of water
23. Carbon-catalyzed gasification of organic feedstocks in supercritical water
24. Reactions of diphenylether in supercritical water - Mechanism and kinetics
25. Pyrolysis of hydrocarbons in supercritical water
26. Gay Pyrolysis of 1,3-butanediol as a model reaction for wood liquefaction in supercritical water
27. Oxidation of hydrogen and carbon monoxide in sub- and supercritical water: Reaction kinetics, pathways, and water-density effects. 2. Elementary reactions modeling
28. Kinetics and mechanism of methane oxidation in supercritical water
29. Elementary reactions in supercritical fluids
30. 2
31. Base-catalyzed reactions in near-critical water for environmentally benign chemical processing
32. Investigating the synthesis potential in supercritical water
33. Hydrolysis of diphenylether in supercritical water. Effects of dissolved NaCl