Oxidation of Phenol over a Transition-Metal Oxide Catalyst in Supercritical Water

Industrial and Engineering Chemistry Research

Volumn 36, Issue 9, 1997, Pages 3439-3445

  Krajnc, Matjaž ^a   Levec, Janez ^b  

^a NATIONAL INSTITUTE OF CHEMISTRY   (Slovenia)

^b UNIVERSITY OF LJUBLJANA   (Slovenia)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; ADSORPTION; CARBOXYLIC ACIDS; CATALYSIS; CATALYST SUPPORTS; FREE RADICAL REACTIONS; OXIDES; PHENOLS; REACTION KINETICS; WATER;

LANGMUIR HINSHELWOOD FORMULATION; SUPERCRITICAL WATER;

OXIDATION;

EID: 0031234995     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie9701130     Document Type: Article

References (27)

1. 3 Catalyst. AIChE J. 1996, 42, 1995.
2. Bielanski, A.; Haber, J. Oxygen in Catalysis; Marcel Dekker, Inc.: New York, 1991.
3. Born, J. G. P.; Louw, R.; Mulder, P. Formation of Dibenzodioxins and Dibenzofurans in Homogeneous Gas-Phase Reactions of Phenols. Chemosphere 1989, 19, 401.
4. Ding, Z. Y.; Aki, S. N. V. K.; Abraham, M. A. Catalytic Supercritical Water Oxidation: Phenol Conversion and Product Selectivity. Environ. Sci. Technol. 1995, 29, 2748.
5. Ding, Z. Y.; Zhong, Y. D.; Frisch, M. A.; Li, L.; Gloyna, E. F. Catalytic Oxidation of Supercritical Water. Ind. Eng. Chem. Res. 1996, 35, 3257.
6. Duggleby, R. G. Regression Analysis of Nonlinear Arrhenius Plots: An Empirical Model and a Computer Program. Comput. Biol. Med. 1984, 14, 447.
7. Golodets, G. I. Heterogeneous Catalytic Reactions Involving Molecular Oxygen; Elsevier: Amsterdam, 1983.
8. Gopalan, S.; Savage, P. E. Reaction Mechanism for Phenol Oxidation in Supercritical Water. J. Phys. Chem. 1994, 98, 12646.
9. Gopalan, S.; Savage, P. E. A Reaction Network Model for Phenol Oxidation in Supercritical Water. AIChE J. 1995, 41, 1864.
10. Jin, L.; Shah, Y. T.; Abraham, M. A. The Effect of Supercritical Water on the Catalytic Oxidation of 1,4-Dichlorobenzene. J. Supercritical Fluids 1990, 3, 233.
11. Jin, L.; Ding, Z. Y.; Abraham, M. A. Catalytic Supercritical Water Oxidation of 1,4-Dichlorobenzene. Chem. Eng. Sci. 1992, 47, 2659.
12. Koo, M.; Lee, W. K.; Lee, C. H. New Reactor System for Supercritical Water Oxidation and its Application on Phenol Destruction. Chem. Eng. Sci. 1997, 52, 1201.
13. Krajnc, M.; Levec, J. Catalytic Oxidation of Toxic Organics in Supercritical Water. Appl. Catal. B: Environ. 1994, 3, L101-L107.
14. Krajnc, M.; Levec, J. On the Kinetic of Phenol Oxidation in Supercritical Water. AIChE J. 1996, 42, 1977.
15. Krajnc, M.; Levec, J. The Role of Catalyst in Supercritical Water Oxidation of Acetic Acid. Appl. Catal. B: Environ. 1997, in press.
16. Li, L.;. Chen, P.; Gloyna, E. F. Generalized Kinetic Model of Wet Oxidation of Organic Compounds. AIChE J. 1991, 37, 1687.
17. Modell, M.; Thomason, T. B. Supercritical Water Destruction of Aqueous Wastes. Hazard Waste 1984, 1, 453.
18. Musso, H. Phenol Coupling. In Oxidative Coupling of Phenols; Taylor, W. I., Battersby, A. R., Eds.; Marcel Dekker, Inc.: New York, 1967.
19. Pintar, A.; Levec, J. Catalytic Liquid-Phase Oxidation of Phenol Aqueous Solutions. A Kinetic Investigation. Ind. Eng. Chem. Res. 1994, 33, 3070.
20. Savage, P. E.; Gopalan, S.; Mizan, T. I.; Martino, C. J.; Brock, E. E. Reactions at Supercritical Conditions: Applications and Fundamentals. AIChE J. 1995, 41, 1723.
21. Sokolovskii, V. D. Principles of Oxidative Catalysis on Solid Oxides. Catal. Rev.-Sci. Eng. 1990, 32, 1.
22. Tester, J. W.; Holgate, H. R.; Armellini, F. J.; Webley, P. A.; Killilea, W. R.; Hong, G. T.; Barner, H. E. Supercritical Water Oxidation Technology: Process Development and Fundamental Research. In Emerging Technologies in Hazardous Waste Management III; Tedder, D. W., Pohland, F. G., Eds.; ACS Symposium Series 518, American Chemical Society: Washington, DC, 1993.
23. Thornton, D. T.; Savage, P. E. Phenol Oxidation in Supercritical Water. J. Supercritical Fluids 1990, 3, 240.
24. Thornton, D. T.; Savage, P. E. Kinetics of Phenol Oxidation in Supercritical Water. AIChE J. 1992, 38, 321.
25. von Sonntag, C.; Schuchmann, H. P. The Elucidation of Peroxyl Radical Reactions in Aqueous Solution with the Help of Radiation-Chemical Methods. Angew. Chem. Int. Ed. Engl. 1991, 30, 1229.
26. Wightman, T. J. Studies in Supercritical Wet Air Oxidation. M.S. Thesis, University of California, Berkeley, CA, 1981.
27. Yang, H. H.; Eckert, C. A. Homogeneous Catalysis in the Oxidation of p-Chlorophenol in Supercritical Water. Ind. Eng. Chem. Res. 1988, 27, 2009.