메뉴 건너뛰기




Volumn 8, Issue 9, 2008, Pages 3302-3308

Phase transitions and CO2 adsorption properties of polymeric magnesium formate

Author keywords

[No Author keywords available]

Indexed keywords


EID: 61549118803     PISSN: 15287483     EISSN: 15287505     Source Type: Journal    
DOI: 10.1021/cg800181q     Document Type: Article
Times cited : (63)

References (73)
  • 5
    • 4444275259 scopus 로고    scopus 로고
    • Recent reviews for gas storage on coordination polymers
    • (a) Recent reviews for gas storage on coordination polymers : Kitagawa, S.; Kitaura, R.; Noro, S.-I. Angew. Chem., Int. Ed. 2004, 43, 2334.
    • (2004) Angew. Chem., Int. Ed , vol.43 , pp. 2334
    • Kitagawa, S.1    Kitaura, R.2    Noro, S.-I.3
  • 14
    • 33750148065 scopus 로고    scopus 로고
    • Wang, Z.; Zhang, Y.; Kurmoo, M.; Liu, T.; Vilminot, S.; Zhao, B.; Gao, S. Aust. J. Chem 2006, 59, 617. See also refs 5e and 5i.
    • (g) Wang, Z.; Zhang, Y.; Kurmoo, M.; Liu, T.; Vilminot, S.; Zhao, B.; Gao, S. Aust. J. Chem 2006, 59, 617. See also refs 5e and 5i.
  • 30
    • 61549138878 scopus 로고    scopus 로고
    • 2O. Kiriyama, R.; Ibamoto, H.; Matsuo, K. Acta Crystallogr. 1954, 7, 482.
    • 2O. Kiriyama, R.; Ibamoto, H.; Matsuo, K. Acta Crystallogr. 1954, 7, 482.
  • 31
    • 37049129815 scopus 로고    scopus 로고
    • 3. Habeeb, J. J.; Tuck, D. G. J. Chem. Soc., Dalton Trans. 1973, 3, 243.
    • 3. Habeeb, J. J.; Tuck, D. G. J. Chem. Soc., Dalton Trans. 1973, 3, 243.
  • 32
    • 0003015589 scopus 로고    scopus 로고
    • Actinide formates. Casellato, U.; Vigato, P.; Vidali, M. Coord. Chem. Rev. 1978, 26 (2), 85.
    • (c) Actinide formates. Casellato, U.; Vigato, P.; Vidali, M. Coord. Chem. Rev. 1978, 26 (2), 85.
  • 33
    • 0021500194 scopus 로고    scopus 로고
    • 2O. Honkonen, R. S.; Ellis, P. D. J. Am. Chem. Soc. 1984, 106, 5488.
    • 2O. Honkonen, R. S.; Ellis, P. D. J. Am. Chem. Soc. 1984, 106, 5488.
  • 34
    • 0001767178 scopus 로고    scopus 로고
    • 2O. Arii, T.; Kishi, A. Thermochim Acta 1999, 325, 157.
    • 2O. Arii, T.; Kishi, A. Thermochim Acta 1999, 325, 157.
  • 35
    • 61549116690 scopus 로고    scopus 로고
    • Rb(HCOO) and Cs(HCOO). Wilson, M. P.; Alcock, N. W.; Rodger, P. M. Inorg. Chem. 2006, 45, 4539.
    • (f) Rb(HCOO) and Cs(HCOO). Wilson, M. P.; Alcock, N. W.; Rodger, P. M. Inorg. Chem. 2006, 45, 4539.
  • 44
    • 0037425223 scopus 로고    scopus 로고
    • Rather, B.; Zaworotko, M. J. Chem. Commun. 2003, 830. See also refs 7a,b, and references therein.
    • (c) Rather, B.; Zaworotko, M. J. Chem. Commun. 2003, 830. See also refs 7a,b, and references therein.
  • 46
    • 9144257887 scopus 로고    scopus 로고
    • An interesting review on the last advances in the XRPD technique is available, see Harris, K. D. M, Cheung, E. Y. Chem. Soc. Rev. 2004, 33, 526
    • An interesting review on the last advances in the XRPD technique is available, see Harris, K. D. M.; Cheung, E. Y. Chem. Soc. Rev. 2004, 33, 526.
  • 47
    • 61549103585 scopus 로고    scopus 로고
    • A comparison of the calculated XRPD spectrum (simulated from the single-crystal data) with the experimental spectrum recorded on the solid product showed that, in the case of the zinc nitrate synthesis, some impurities are present, whose relative amount is presumably very small (less than 10%) with respect to the main phase. This can be inferred from the satisfactory match of the measured elemental analyses with the theoretical ones. Products from zinc perchlorate are generally less pure than those coming from nitrate, probably up to 40-50%, from the X-ray intensities (Figure 1, spectrum b).
    • A comparison of the calculated XRPD spectrum (simulated from the single-crystal data) with the experimental spectrum recorded on the solid product showed that, in the case of the zinc nitrate synthesis, some impurities are present, whose relative amount is presumably very small (less than 10%) with respect to the main phase. This can be inferred from the satisfactory match of the measured elemental analyses with the theoretical ones. Products from zinc perchlorate are generally less pure than those coming from nitrate, probably up to 40-50%, from the X-ray intensities (Figure 1, spectrum b).
  • 52
    • 61549121217 scopus 로고    scopus 로고
    • ORTEP-III. Burnett, M. N.; Johnson, C. K. Report ORNL-6895; Oak Ridge National Laboratory: Oak Ridge, TN, 1996;
    • (a) ORTEP-III. Burnett, M. N.; Johnson, C. K. Report ORNL-6895; Oak Ridge National Laboratory: Oak Ridge, TN, 1996;
  • 57
    • 0038344721 scopus 로고    scopus 로고
    • (c) Corma, A. J. Catal. 2003, 216, 298.
    • (2003) J. Catal , vol.216 , pp. 298
    • Corma, A.1
  • 58
    • 11944262684 scopus 로고    scopus 로고
    • Some early examples of solvothermal (or hydrothermal) syntheses applied to MOFs are the following: Yaghi, O. M.; Li, H. J. Am. Chem. Soc. 1995, 117, 10401.
    • (a) Some early examples of solvothermal (or hydrothermal) syntheses applied to MOFs are the following: Yaghi, O. M.; Li, H. J. Am. Chem. Soc. 1995, 117, 10401.
  • 70
    • 61549123144 scopus 로고    scopus 로고
    • GSAS; Larson, C, von Dreele, R. B. Generalized Crystal Structure Analysis System; Los Alamos National Laboratory: New Mexico, 2001. Rietveld refinement of 2a was performed using the GSAS program. Firstly, zero shift, cell parameters, background, and profile shape were refined; a corrected pseudo-Voigt profile function (six terms) with two terms for the correction of asymmetry at the low-angle region was used. Secondly, atomic coordinates and isotropic thermal factors were refined restraining the distances and the angles to the following values: Mg-O, 2.05(5) Å, C-O, 1.23(2) Å, O-C-O, 120(1)°. The statistical weight of these restraints was decreased as the refinement proceeded, but it was not possible to set it to zero, due to some unrealistic light atom bond distances. At the end of the refinement, the shifts in all parameters were less than their standard deviations. Crystal data and refinement details for 2a: Monoclinic P2
    • 1/2).
  • 73
    • 61549098514 scopus 로고    scopus 로고
    • Unpublished H2 adsorption experiments on 2 showed that in this case performance is much worse than with CO2. A maximum value of 0.070 wt, corresponding to 0.347 mmol/g of hydrogen adsorbed at-196 °C and at ρH2, 700 torr was recorded. Thus, selective gas sorption (i.e, gas separation) in a H2/CO2 mixture is achievable with 2
    • 2 mixture is achievable with 2.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.