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62149112278
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Using a catalytic amount of FeCl3 (0.1 equiv, we obtained the corresponding acetal as a single product in good yield 80, See ref 5
-
3 (0.1 equiv), we obtained the corresponding acetal as a single product in good yield (80%). See ref 5.
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38
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62149098412
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3 and isovaleraldehyde, in the presence of air and moisture the target product was obtained in a remarkable 70% yield.
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3 and isovaleraldehyde, in the presence of air and moisture the target product was obtained in a remarkable 70% yield.
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-
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39
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62149085975
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The reaction does not work with other functional groups as benzyl, THP, or TBS
-
The reaction does not work with other functional groups as benzyl, THP, or TBS.
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-
-
-
40
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33846093447
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Miranda, P. O.; Carballo, R. M.; Ramírez, M. A.; Martin, V. S.; Padron, J. I. Arkivoc 2007, iv, 331-334.
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43
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0028957650
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2 at room temperature is a suitable method to achieve debenzylations. See: Padron, J. I.; Vázquez, J. T. Tetrahedron Asymmetry 1995, 6, 857-858.
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2 at room temperature is a suitable method to achieve debenzylations. See: Padron, J. I.; Vázquez, J. T. Tetrahedron Asymmetry 1995, 6, 857-858.
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44
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62149135392
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It should be emphasized that the storage of R3SiX generate traces of free acid HX by hydrolysis: Oilman, A. D, Ioffe, S. L Chem. Rev. 2003, 103, 733-772
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3SiX generate traces of free acid HX by hydrolysis: Oilman, A. D.; Ioffe, S. L Chem. Rev. 2003, 103, 733-772.
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-
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45
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0018615345
-
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3 is hydrolyzed to the corresponding iron (III) halide: Miller, D. D.; Van Campen, D Am. J. Clin. Nutr. 1979, 32, 2354-2361. (Chemical Equation Presented)
-
3 is hydrolyzed to the corresponding iron (III) halide: Miller, D. D.; Van Campen, D Am. J. Clin. Nutr. 1979, 32, 2354-2361. (Chemical Equation Presented)
-
-
-
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46
-
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62149126678
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3, the corresponding acetal was isolated only when Z is oxygen.
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3, the corresponding acetal was isolated only when Z is oxygen.
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