A bench-stable Pd catalyst for the hydroarylation of fullerene with boronic acids

Organic Letters

Volumn 10, Issue 20, 2008, Pages 4609-4612

  Mori, Susumu ^a,b   Nambo, Masakazu ^a,b   Chi, Liang Chen ^a,b   Bouffard, Jean ^a,b   Itami, Kenichiro ^a,b  

^a NAGOYA UNIVERSITY   (Japan)

^b JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 61349159292     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol801936j     Document Type: Article

References (61)

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58. 6 was not conducted.
59. 60) converted (Orchin, M.; Macomber, R. S.; Pinhas, A. R.; Wilson, R. M. The Vocabulary and Concepts of Organic Chemistry, ed.; Wiley-Interscience: Hoboken, NJ, 2005). The most common side products for reactions where the selectivity is low are multiple hydroarylation products.
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61. For example, we have identified that the Pd catalyst 2 is active in the hydroarylation (conjugate addition) of cyclic and acyclic enones with boronic acids. The reactions proceed at room temperature under air (see the Supporting Information for details):