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Volumn 10, Issue 21, 2008, Pages 4923-4926

Mono- and penta-addition of enol silyl ethers to [60]fullerene

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EID: 60949110791     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol8020379     Document Type: Article
Times cited : (13)

References (36)
  • 17
    • 60949101245 scopus 로고    scopus 로고
    • While we consider that the decomposition is due to oxidation of 2, the reason why 2 survives the oxidative reaction conditions is unclear
    • While we consider that the decomposition is due to oxidation of 2, the reason why 2 survives the oxidative reaction conditions is unclear.
  • 19
    • 60949101769 scopus 로고    scopus 로고
    • The low methylation yield is due to the electron-withdrawing ester functionality, which lowers the nucleophilicity of the penta-adduct anion
    • The low methylation yield is due to the electron-withdrawing ester functionality, which lowers the nucleophilicity of the penta-adduct anion.
  • 22
    • 0027788279 scopus 로고    scopus 로고
    • 2 and 2,3-dichloro-5,6- dicyanobenzoquinone. (a) Becker, L.; Evans, T. P.; Bada, J. L. J. Org. Chem. 1993, 58, 7630-7631.
    • 2 and 2,3-dichloro-5,6- dicyanobenzoquinone. (a) Becker, L.; Evans, T. P.; Bada, J. L. J. Org. Chem. 1993, 58, 7630-7631.
  • 24
    • 60949112079 scopus 로고    scopus 로고
    • In the 20% DMSO/chlorobenzene solvent system, formation of a small amount of penta-adduct 2 was observed even under deoxygenated conditions
    • In the 20% DMSO/chlorobenzene solvent system, formation of a small amount of penta-adduct 2 was observed even under deoxygenated conditions.
  • 25
    • 60949094166 scopus 로고    scopus 로고
    • Isolation of dimerized tetra-adduct 8 was difficult since the product was unstable to air-oxidation and also the dimer comprises a complex mixture of isomers.
    • Isolation of dimerized tetra-adduct 8 was difficult since the product was unstable to air-oxidation and also the dimer comprises a complex mixture of isomers.
  • 29
    • 0000927144 scopus 로고    scopus 로고
    • Tanaka, T.; Komatsu, K
    • Dimerization of the tetra-adduct 8 most likely follows the mechanism of COD dimerization to form C120H2, Perkin Trans
    • 2. Tanaka, T.; Komatsu, K. J. Chem. Soc., Perkin Trans. 1999, 1, 1671-1675.
    • (1999) J. Chem. Soc , vol.1 , pp. 1671-1675
  • 30
    • 60949100967 scopus 로고    scopus 로고
    • Some overreacted byproducts were observed in the syntheses of monoadducts due to the presence of DMSO, which presumably acts as an oxidant
    • Some overreacted byproducts were observed in the syntheses of monoadducts due to the presence of DMSO, which presumably acts as an oxidant.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.