Evidence for formation and different evolution of tertiary rhodium alkyl intermediates under rhodium-catalyzed deuterio-(hydro)formylation of 1-(n-pyridyl)-1-phenylethenes

Journal of Organometallic Chemistry

Volumn 690, Issue 7, 2005, Pages 1699-1704

  Lazzaroni, Raffaello ^a   Settambolo, Roberta ^a   Rocchiccioli, Silvia ^a   Paganelli, Stefano ^b   Marchetti, Mauro ^c  

^a UNIVERSITY OF PISA   (Italy)

^b CA' FOSCARI UNIVERSITY OF VENICE   (Italy)

^c ICB CNR   (Italy)

Author keywords

Catalysis; Deuterioformylation; Hydroformylation; Tertiary rhodium alkyl

Indexed keywords

CARBON MONOXIDE; CATALYSTS; DEUTERIUM; NITROGEN; NUCLEAR MAGNETIC RESONANCE; OLEFINS; OXIDATION; SUBSTRATES;

CHEMO-AND REGIOSELECTIVITIES; MIGRATORY INSERTION; PHOSPHINES; VINYLIDENIC;

RHODIUM COMPOUNDS;

CYANOACRYLATE; DEUTERIUM; ETHYLENE; NITROGEN; PHOSPHINE; RHODIUM; VINYL DERIVATIVE;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL BOND; CHEMICAL REACTION KINETICS; DEUTERON NUCLEAR MAGNETIC RESONANCE; OXIDATION KINETICS; TEMPERATURE DEPENDENCE;

EID: 15744366141     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2005.01.020     Document Type: Article

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