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C. Duplais F. Bures T. J. Korn I. Sapountzis G. Cahiez P. Knochel Angew. Chem., Int. Ed. 2004 43 2968 2970
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3 give 3 in 60, 29, 25, 1, and 1% yield, respectively. Details are given in Supporting Information
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In situ reduction of Fe(iii) to Fe(ii) is reported to be quite rapid in the presence of organomagnesium or organolithium reagents; see ref. 3p The reaction of 2 with 1e took place at 80°C for 36 h to give the corresponding coupling product in 60% yield. Details are given in Supporting Information The reaction of 17 with 1a and 1c gave 86% and 77% yield, respectively. Details are given in Supporting Information
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Details are given in Supporting Information
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A patent application has been filed for the DPPBz derivatives and their iron complexes. M. Nakamura, T. Hatakeyama and Y. Fujiwara, JP Pat., 2008-174021 After this manuscript was submitted for publication Bedford et al. reported that the iron-DPPBz catalyst is effective for cross-couplings of benzyl halides.
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A patent application has been filed for the DPPBz derivatives and their iron complexes. M. Nakamura, T. Hatakeyama and Y. Fujiwara, JP Pat., 2008-174021
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