Allylic oxidations catalyzed by dirhodium caprolactamate via aqueous tert-butyl hydroperoxide: The role of the tert-butylperoxy radical

Journal of Organic Chemistry

Volumn 74, Issue 2, 2009, Pages 730-738

  McLaughlin, Emily C ^a   Choi, Hojae ^a   Wang, Kan ^a   Chiou, Grace ^a   Doyle, Michael P ^a  

^a Bldg 142   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYLIC OXIDATIONS; COMPARATIVE STUDIES; DIRHODIUM; DISPROPORTIONATION PATHWAYS; HIGH YIELDS; HYDROGEN ATOM ABSTRACTIONS; METAL CATALYSTS; OPTIMAL EFFICIENCIES; OXIDATION REACTIONS; PRODUCT FORMATIONS; TERT-BUTYL HYDROPEROXIDE; TERT-BUTYLPEROXY RADICALS;

CARBOXYLIC ACIDS; CATALYSIS; CATALYSTS; FORMING; HYDROGEN; HYDROGEN PRODUCTION; KETONES; ORGANIC ACIDS; SULFUR COMPOUNDS;

OXIDATION;

CARBENE; CARBONYL DERIVATIVE; CARBOXYLIC ACID; DIRHODIUM CAPROLACTAMATE; KETONE; RHODIUM DERIVATIVE; TERT BUTYL HYDROPEROXIDE; UNCLASSIFIED DRUG; ACETYLCYCLOHEXENE; ALKENE; CAPROLACTAM; CYCLOHEXENE DERIVATIVE; DITHODIUM CAPROLACTAMATE; DRUG DERIVATIVE; ORGANOMETALLIC COMPOUND; OXIDIZING AGENT; WATER;

ALLYLIC REARRANGEMENT; AQUEOUS SOLUTION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL STRUCTURE; HYDROLYSIS; MOLECULAR MECHANICS; OXIDATION; STEREOCHEMISTRY; SUBSTITUTION REACTION; SYNTHESIS; CHEMISTRY; TEMPERATURE;

ALKENES; CAPROLACTAM; CATALYSIS; CYCLOHEXENES; ORGANOMETALLIC COMPOUNDS; OXIDANTS; TEMPERATURE; TERT-BUTYLHYDROPEROXIDE; WATER;

EID: 60849086200     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo8021132     Document Type: Article

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