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Crystal data for [Cu(peadaa)]n (2, monoclinic, P21, 298.77 gmol-1, a, 7.090(2) Å, b, 7.142(2) Å, c, 11.224(2) Å, β, 90.145(3)°, V, 568.4(2) Å3, Z, 2, ρcalcd, 1.746 g cm-3, μ(Mo-K α, 1.927 mm-1, 5092 reflections measured, 2583 [Rint, 0.0503] unique, which were used in all calculations. GooF on F2, 1.002, final R1, 0.0387 and wR2, 0.0848 (all data, Flack absolute structure parameter x, 0.039(18, Data were measured at 193(2) K with a Bruker CCD-1000 diffractometer [λMo-Kα, 0.71073 Å] with a graphite monochromator. CCDC-704969 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallogr
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α) = 0.71073 Å] with a graphite monochromator. CCDC-704969 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data- request/cif.
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16
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85163247367
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A search of the CSD (v7.29, November 07+1 update) for carboxylate-bridged TM tetramers found 701 structures. Only two were 44 nets, and neither showed the pattern of long and short M⋯M connections observed in 2.
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A search of the CSD (v7.29, November 07+1 update) for carboxylate-bridged TM tetramers found 701 structures. Only two were 44 nets, and neither showed the pattern of long and short M⋯M connections observed in 2.
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17
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0001792356
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Calculated using PLATON
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Calculated using PLATON: A. L. Spek, J. Appl. Crystallogr. 2003, 36, 7-13.
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0036979738
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M. Du, X.-H. Bu, Y.-M. Guo, J. Ribas, C. Diaz, Chem. Commun. 2002, 2550.
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20
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0000335122
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S. Wang, S. J. Trepanier, J.-C. Zheng, Z. Pang, M. J. Wagner, Inorg. Chem. 1992, 31, 2118-2127.
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21
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0037179979
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M. Murugesu, R. Clérac, B. Pilawa, A. Mandel, C. E. Anson, A. K. Powell, Inorg. Chim. Acta 2002, 337, 328-336.
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22
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0013408848
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and references cited therein
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23
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4544240277
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CONDON was used for magnetic susceptibility analysis, see
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CONDON was used for magnetic susceptibility analysis, see: H. Schilder, H. Lueken, J. Magn. Magn. Mater. 2004, 281, 17-26.
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