Reaction of benzyne with salicylaldehydes: General synthesis of xanthenes, xanthones, and xanthols

Organic Letters

Volumn 11, Issue 1, 2009, Pages 169-171

  Okuma, Kentaro ^a   Nojima, Akiko ^a   Matsunaga, Nahoko ^a   Shioji, Kosei ^a  

^a FUKUOKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDE; BENZENE DERIVATIVE; BENZYNE; UNCLASSIFIED DRUG; XANTHENE DERIVATIVE; XANTHONE DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; STEREOISOMERISM; SYNTHESIS;

ALDEHYDES; BENZENE DERIVATIVES; MOLECULAR STRUCTURE; STEREOISOMERISM; XANTHENES; XANTHONES;

EID: 59649114970     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol802597x     Document Type: Article

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37. 3 (3.0 mmol) in 5 mL of acetonitrile was added CsF (3.0 mmol). The reaction mixture was stirred at room temperature for 15 h, and the reaction mixture was poured into aqueous Na2CO3 and extracted with ether. The combined organic layers were dried over sodium sulfate, evaporated, and purified by alumina chromatography to give 5.