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The preparation of compound 1: a mixture of hydrochloride salt of imidazo[1,2-a]pyridin-2(3H)-one (0.15 mmol) and Zn(OO4)2 · 6H2O (0.15 mmol) was placed in a heavy-walled Pyrex tube containing DMF (0.3 mL) and H2O (0.3 mL, The tube was frozen in liquid N2, sealed under a vacuum, and then heated at 120 °C for 2 days; red crystals of 1 were produced (yield: 35% based on hydrochloride salt of imidazo[1,2-a]pyridin-2(3H)-one, Anal. Calcd for C14H 9ClN4OZn: C, 47.99; H, 2.57; N, 15.99. Found: C, 47.32; H, 2.59; N, 15.57. IR (KBr pellet, Cm-1, 3438s, 1631s, 1560s, 1497s, 1454m, 1364m, 1284w, 1235m, 1153w, 1131w, 1103w, 1000w, 928w, 758w, 743m, 704w, 540m, 440w. CAUTION! Zn(ClO4)2·6H2O is potentially explosive and should be used with care
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2O is potentially explosive and should be used with care.
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39
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2), 190 parameters. The structure was solved and refined using the SHELXTL crystallographic software package.
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2), 190 parameters. The structure was solved and refined using the SHELXTL crystallographic software package.
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